Triptane

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Triptane
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Template:Longitem 1730756
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UN number 1206
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Template:Longitem Template:Chembox Elements/molecular formula
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Appearance Colorless liquid
Odor Odorless
Density 0.693 g mL−1
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Vapor pressure 23.2286 kPa (at 37.7 °C)
Template:Longitem 4.1 nmol Pa−1 kg−1
Template:Longitem −88.36·10−6 cm3/mol
Template:Longitem 1.389
Template:Longitem 213.51 J K−1 mol−1
Template:Longitem 292.25 J K−1 mol−1
Template:Longitem −238.0 – −235.8 kJ mol−1
Template:Longitem −4.80449 – −4.80349 MJ mol−1
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Explosive limits 1–7%
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Triptane, or 2,2,3-trimethylbutane, is an organic chemical compound with the molecular formula C7H16 or (H3C-)3C-C(-CH3)2H. It is therefore an alkane, specifically the most compact and heavily branched of the heptane isomers, the only one with a butane (C4) backbone.

It was first synthesized in 1922 by Belgian chemists Georges Chavanne (1875–1941) and B. Lejeune, who called it trimethylisopropylmethane.[2][3]

Due to its high octane rating (112–113 RON, 101 MON[4][5]) triptane was produced on alkylation units starting from 1943[6] for use as an anti-knock additive in gasoline. It was extensively researched for this role and received the modern name in the late 1930s at a joint laboratory of NACA, National Bureau of Standards, US Army Air Corps and the Bureau of Aeronautics.[7]

As of 2011, it was not a significant component of US automobile gasoline, present only in trace amounts (0.05–0.1%).[8]

See also

References

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  3. ↑ https://webbook.nist.gov/cgi/cbook.cgi?Source=1922CHA%2FLEJ98
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