Tetramethylammonium pentafluoroxenate

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Tetramethylammonium pentafluoroxenate
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Molar mass 300.4308 g/mol

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Script error: No such module "Unsubst". Tetramethylammonium pentafluoroxenate is a chemical compound with the chemical formula Template:Chem2. This salt consists of tetramethylammonium cations Template:Chem2 and pentafluoroxenate(IV) anions Template:Chem2. The Template:Chem2 ion was the first example of a pentagonal planar molecular geometry [[VSEPR theory|Template:Chem2]] species.[1] It was prepared by the reaction of [[Tetramethylammonium fluoride|Template:Chem2]] with xenon tetrafluoride, Template:Chem2 being chosen because it can be prepared in anhydrous form and is readily soluble in organic solvents.[1] The anion is planar, with the fluorine atoms in a slightly distorted pentagonal coordination (Xe–F bond lengths 197.9–203.4 pm, and F–X–F bond angles 71.5°–72.3°).[1] Other salts have been prepared with sodium, caesium and rubidium, and vibrational spectra show that these contain the same planar ion.[1] The isolated anion has the point group of D5h.[1]

Ball-and-stick model of the pentafluoroxenate ion Structural formula of the pentafluoroxenate ion

References

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