Tellurium tetrabromide

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Tellurium tetrabromide (TeBr4) is an inorganic chemical compound. It has a similar tetrameric structure to TeCl4.[1] It can be made by reacting bromine and tellurium.[2] In the vapour TeBr4 dissociates:[1]

TeBr4 → TeBr2 + Br2

It is a conductor when molten, dissociating into the ions TeBr3+ and Br. When dissolved in benzene and toluene, TeBr4 is present as the unionized tetramer Te4Br16.[1] In solvents with donor properties such as acetonitrile, CH3CN ionic complexes are formed which make the solution conducting:

TeBr4 + 2CH3CN → (CH3CN)2TeBr3+ + Br

References

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  1. a b c Inorganic Chemistry,Egon Wiberg, Arnold Frederick Holleman Elsevier 2001 Template:ISBN
  2. Template:Greenwood&Earnshaw