Strontium fluoride

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Strontium fluoride

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Template:Longitem	SrF2
Molar mass	125.62 g/mol
Density	4.24 g/cm3
Melting point	Template:Chembox CalcTemperatures
Boiling point	Template:Chembox CalcTemperatures
Template:Longitem	4.33Template:E
Template:Longitem	−37.2·10−6 cm3/mol
Template:Longitem	1.439 @0.58 μm
Template:Longitem	cubic crystal system, cF12
Template:Longitem	Fm3m, #225
Template:Longitem	a = 5.80 Å, b = 5.80 Å, c = 5.80 Å α = 90°, β = 90°, γ = 90°
Template:Longitem	Sr, 8, cubic F, 4, tetrahedral
Flash point	Template:Chembox CalcTemperatures
Template:Longitem	Strontium chloride Strontium bromide Strontium iodide
Template:Longitem	beryllium fluoride magnesium fluoride calcium fluoride barium fluoride

Strontium fluoride, SrF₂, also called strontium difluoride and strontium(II) fluoride, is a fluoride of strontium. It is a brittle white crystalline solid. In nature, it appears as the very rare mineral strontiofluorite.

Preparation

Strontium fluoride is prepared by the action of hydrofluoric acid on strontium carbonate.

Structure

The solid adopts the fluorite structure. In the vapour phase the SrF₂ molecule is non-linear with an F−Sr−F angle of approximately 120°. This is an exception to VSEPR theory which would predict a linear structure. Ab initio calculations have been cited to propose that contributions from d orbitals in the shell below the valence shell are responsible. Another proposal is that polarization of the electron core of the strontium atom creates an approximately tetrahedral distribution of charge that interacts with the Sr−F bonds.

Properties

It is almost insoluble in water (its K_sp value is approximately 2.0x10⁻¹⁰ at 25 degrees Celsius).

It irritates eyes and skin, and is harmful when inhaled or ingested.
Similar to CaF₂ and BaF₂, SrF₂ displays superionic conductivity at elevated temperatures.

Strontium fluoride is transparent to light in the wavelengths from vacuum ultraviolet (150 nm) to infrared (11 μm). Its optical properties are intermediate to calcium fluoride and barium fluoride.

Uses

Strontium fluoride is used as an optical material for a small range of special applications, for example, as an optical coating on lenses and also as a thermoluminescent dosimeter crystal.

Another use is as a carrier of strontium-90 radioisotope in radioisotope thermoelectric generators.