Silver oxide
Script error: No such module "about". Template:Chembox Silver oxide is the chemical compound with the formula Ag2O. It is a fine black or dark brown powder that is used to prepare other silver compounds.
Preparation
_oxide.JPG){kind=link}
Silver oxide can be prepared by combining aqueous solutions of silver nitrate and an alkali hydroxide.[1][2] This reaction does not afford appreciable amounts of silver hydroxide due to the favorable energetics for the following reaction:[3]
- Template:Chem2Script error: No such module "String".(pK = 2.875[4])
With suitably controlled conditions, this reaction can be used to prepare Ag2O powder with properties suitable for several uses including as a fine grained conductive paste filler.[5]
Structure and properties
Ag2O features linear, two-coordinate Ag centers linked by tetrahedral oxides. It is isostructural with Cu2O. It "dissolves" in solvents that degrade it. It is slightly soluble in water due to the formation of the ion Template:Chem2 and possibly related hydrolysis products.[6] It is soluble in ammonia solution, producing active compound of Tollens' reagent. A slurry of Ag2O is readily attacked by acids:
where HX = HF, HCl, HBr, HI, or CF3COOH. It will also react with solutions of alkali chlorides to precipitate silver chloride, leaving a solution of the corresponding alkali hydroxide.[6][7]
Despite the photosensitivity of many silver compounds, silver oxide is not photosensitive,[8] although it readily decomposes at temperatures above 280 °C.[9]
Applications
This oxide is used in silver-oxide batteries.[10] In organic chemistry, silver oxide is used as a mild oxidizing agent.[11] For example, it oxidizes aldehydes to carboxylic acids.[12]
References
<templatestyles src="Reflist/styles.css" />
- ↑ O. Glemser and H. Sauer "Silver Oxide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1037.
- ↑ Script error: No such module "Citation/CS1".; Script error: No such module "citation/CS1"..
- ↑ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. Template:ISBN.
- ↑ Script error: No such module "Citation/CS1".
- ↑ <templatestyles src="Citation/styles.css"/>Template:Citation/make link, Harigae, Kenichi & Shoji, Yoshiyuki, "Fine-grain silver oxide powder", published Script error: No such module "auto date formatter".Script error: No such module "Check for unknown parameters".
- ↑ a b Script error: No such module "citation/CS1".
- ↑ General Chemistry by Linus Pauling, 1970 Dover ed. p703-704
- ↑ Script error: No such module "Citation/CS1".
- ↑ Merck Index of Chemicals and Drugs Template:Webarchive, 14th ed. monograph 8521
- ↑ Script error: No such module "citation/CS1".
- ↑ Script error: No such module "citation/CS1".
- ↑ Script error: No such module "Citation/CS1".
Script error: No such module "Check for unknown parameters".
External links
- Annealing of Silver Oxide – Demonstration experiment: Instruction and video