Potassium peroxide

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Potassium peroxide
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Template:Longitem K2O2
Molar mass 110.196 g/mol
Appearance yellow amorphous solid
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Template:Longitem Orthorhombic
Template:Longitem Cmca, oS16
Template:Longitem 113 J·mol−1·K−1[2]
Template:Longitem −496 kJ·mol−1[2]
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Template:Longitem Potassium chloride
Template:Longitem Lithium peroxide
Sodium peroxide
Rubidium peroxide
Caesium peroxide
Template:Longitem Potassium oxide
Potassium superoxide
Potassium ozonide

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Potassium peroxide is an inorganic compound with the molecular formula K2O2. It is formed as potassium reacts with oxygen in the air, along with potassium oxide (K2O) and potassium superoxide (KO2).

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Crystal structure

Potassium peroxide reacts with water to form potassium hydroxide and oxygen:

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Properties

Potassium peroxide is a highly reactive, oxidizing white to yellowish solid which, while not flammable itself, reacts violently with flammable materials. It decomposes violently on contact with water.[1]

The standard enthalpy of formation of potassium peroxide is ΔH f 0 = −496 kJ/mol.

Usage

Potassium peroxide is used as an oxidizing agent and bleach (due to the peroxide), and to purify air.

References

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