Nitronium tetrafluoroborate

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Nitronium tetrafluoroborate
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Molar mass 132.81
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Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion.[1] It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents.

Preparation

Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide.[2]

Applications

Nitronium tetrafluoroborate is used in organic synthesis as an electrophilic nitrating agent and a mild oxidant.[3]

References

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