Nitramide
Template:Short description <templatestyles src="Chembox/styles.css"/>
Template:Chembox image cellTemplate:Chembox AllOtherNamesTemplate:Chembox headerbarTemplate:Chembox IndexlistTemplate:Chembox JmolTemplate:Chembox ChEMBLTemplate:Chembox ECHATemplate:Chembox E numberTemplate:Chembox IUPHAR ligandTemplate:Chembox UNIITemplate:Chembox CompToxTemplate:Chembox headerbarTemplate:Chembox headerbarTemplate:Chembox Datapage checkTemplate:Yesno| Template:Chembox image sbs cell | |
| Template:Longitem | Template:Unbulleted list |
| ChEBI | Template:Unbulleted list |
| ChemSpider | Template:Unbulleted list |
| DrugBank | Template:Unbulleted list |
| EC Number | Template:Unbulleted list |
| KEGG | Template:Unbulleted list |
| Template:Longitem | Template:Unbulleted list |
| RTECS number | Template:Unbulleted list |
| Script error: No such module "collapsible list". | |
| Script error: No such module "collapsible list". | |
| Template:Longitem | Template:Chem2 |
| Molar mass | Template:Chem molar mass |
| Appearance | Colorless solid[1] |
| Density | 1.378 g/cm3 |
| Melting point | Template:Chembox CalcTemperatures |
| Acidity (pKa) | 6.5[2] |
| Template:Longitem | Template:Ubl |
Template:Chembox Footer/tracking container onlyScript error: No such module "TemplatePar".Template:Short description
Nitramide or nitroamine is a chemical compound with the molecular formula Template:Chem2. Substituted derivatives Template:Chem2 are termed nitramides or nitroamines as well. Organyl derivatives of nitramide, Template:Chem2 and Template:Chem2, are widely used as explosives: examples include RDX and HMX. It is an isomer of hyponitrous acid. Nitramide can be viewed as a nitrogen analog of nitric acid (Template:Chem2), in which the hydroxyl group Template:Chem2 is replaced with the amino group Template:Chem2.
Structure
The nitramide molecule is essentially an amine group (Template:Chem2) bonded to a nitro group (Template:Chem2). It is reported to be non-planar in the gas phase,[3] but planar in the crystal phase.[1]
Synthesis
Thiele and Lachman's original synthesis of nitramide involved the hydrolysis of potassium nitrocarbamate:[1]
Other routes to nitramide include hydrolysis of nitrocarbamic acid,
reaction of sodium sulfamate with nitric acid,
and reaction of dinitrogen pentoxide with two equivalents of ammonia.
Organic nitramides
Script error: No such module "Labelled list hatnote". Also called nitramines, organic nitramides are important explosives. They are prepared by nitrolysis of hexamethylenetetramine.
References
<templatestyles src="Reflist/styles.css" />
Script error: No such module "Check for unknown parameters".