Isotopes of berkelium

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Template:Short description Template:Infobox berkelium isotopes Berkelium (97Bk) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 243Bk in 1949. There are nineteen known radioisotopes, from 233Bk to 253Bk (except 235Bk and 237Bk), and seven nuclear isomers. The longest-lived isotope known is 247Bk with a half-life of 1,380 years; however 248Bk, which has not been observed to decay, may live longer.

List of isotopes

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Template:Isotopes table |-id=Berkelium-233 | rowspan=2|233Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 136 | rowspan=2|233.05665(25)# | rowspan=2|Script error: No such module "val". | α (82%) | 229Am | rowspan=2|3/2−# |- | β+? (18%) | 233Cm |-id=Berkelium-234 | rowspan=2|234Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 137 | rowspan=2|234.05732(16)# | rowspan=2|Script error: No such module "val". | α (>80%) | 230Am | rowspan=2|3−# |- | β+ (<20%) | 234Cm |-id=Berkelium-236 | rowspan=2|236Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 139 | rowspan=2|236.05748(39)# | rowspan=2|Script error: No such module "val". | β+ (99.96%) | 236Cm | rowspan=2|4+# |- | β+, SF (0.04%) | (various) |-id=Berkelium-238 | rowspan=2|238Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 141 | rowspan=2|238.05820(28)# | rowspan=2|Script error: No such module "val". | β+ (99.95%) | 238Cm | rowspan=2| 1# |- | β+, SF (0.048%) | (various) |-id=Berkelium-239 | 239Bk | style="text-align:right" | 97 | style="text-align:right" | 142 | 239.05824(22)# | 100# s | β+ | 239Cm | (7/2+) |-id=Berkelium-240 | rowspan=3|240Bk | rowspan=3 style="text-align:right" | 97 | rowspan=3 style="text-align:right" | 143 | rowspan=3|240.05976(16)# | rowspan=3|Script error: No such module "val". | β+? | 240Cm | rowspan=3|7−# |- | α? | 236Am |- | β+, SF (0.0013%) | (various) |-id=Berkelium-241 | 241Bk | style="text-align:right" | 97 | style="text-align:right" | 144 | 241.06010(18)# | Script error: No such module "val". | β+ | 241Cm | (7/2+) |-id=Berkelium-242 | rowspan=2|242Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 145 | rowspan=2|242.06200(14)# | rowspan=2|Script error: No such module "val". | β+ | 242Cm | rowspan=2|3+# |- | β+, SF (<3×10−5%) | (various) |-id=Berkelium-242m | style="text-indent:1em" | 242mBk | colspan="3" style="text-indent:2em" | 2000(200)# keV | Script error: No such module "val". | SF | (various) | |-id=Berkelium-243 | rowspan=2|243Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 146 | rowspan=2|243.063006(5) | rowspan=2|Script error: No such module "val". | β+ (99.85%) | 243Cm | rowspan=2|3/2− |- | α (0.15%) | 239Am |-id=Berkelium-244 | rowspan=2|244Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 147 | rowspan=2|244.065179(15) | rowspan=2|Script error: No such module "val". | β+? (99.994%) | 244Cm | rowspan=2|4− |- | α (0.006%) | 240Am |-id=Berkelium-244m | style="text-indent:1em" | 244mBk | colspan="3" style="text-indent:2em" | 1500(500)# keV | Script error: No such module "val". | SF | (various) | |-id=Berkelium-245 | rowspan=2|245Bk | rowspan=2 style="text-align:right" | 97 | rowspan=2 style="text-align:right" | 148 | rowspan=2|245.0663598(19) | rowspan=2|Script error: No such module "val". | EC (99.88%) | 245Cm | rowspan=2|3/2− |- | α (0.12%) | 241Am |-id=Berkelium-246 | 246Bk | style="text-align:right" | 97 | style="text-align:right" | 149 | 246.06867(6) | Script error: No such module "val". | β+ | 246Cm | 2(−) |-id=Berkelium-247 | 247Bk | style="text-align:right" | 97 | style="text-align:right" | 150 | 247.070306(6) | Script error: No such module "val". | α | 243Am | 3/2− |-id=Berkelium-248 | rowspan=3|248Bk | rowspan=3 style="text-align:right" | 97 | rowspan=3 style="text-align:right" | 151 | rowspan=3|248.07314(5) | rowspan=3|>9 y | α? | 244Am | rowspan=3|6+# |- | EC? | 248Cm |- | β? | 248Cf |-id=Berkelium-248m | rowspan=2 style="text-indent:1em" | 248mBk[n 1]Template:R/superscript | rowspan=2 colspan="3" style="text-indent:2em" | −20(50) keV | rowspan=2| 23.7(2) h | β (70%) | 248Cf | rowspan=2| 1(−) |- | EC (30%) | 248Cm |-id=Berkelium-249 | rowspan=3|249Bk | rowspan=3 style="text-align:right" | 97 | rowspan=3 style="text-align:right" | 152 | rowspan=3|249.0749831(13) | rowspan=3|Script error: No such module "val". | β | 249Cf | rowspan=3|7/2+ |- | α (0.00145%) | 245Am |- | SF (4.7×10−8%) | (various) |-id=Berkelium-249m | style="text-indent:1em" | 249mBk | colspan="3" style="text-indent:2em" | 8.777(14) keV | Script error: No such module "val". | IT | 249Bk | 3/2− |-id=Berkelium-250 | 250Bk | style="text-align:right" | 97 | style="text-align:right" | 153 | 250.078317(3) | Script error: No such module "val". | β | 250Cf | 2− |-id=Berkelium-250m1 | style="text-indent:1em" | 250m1Bk | colspan="3" style="text-indent:2em" | 35.59(10) keV | Script error: No such module "val". | IT | 250Bk | 4+ |-id=Berkelium-250m2 | style="text-indent:1em" | 250m2Bk | colspan="3" style="text-indent:2em" | 85.6(16) keV | Script error: No such module "val". | IT | 250Bk | 7+ |-id=Berkelium-251 | 251Bk | style="text-align:right" | 97 | style="text-align:right" | 154 | 251.080761(12) | Script error: No such module "val". | β | 251Cf | (3/2−) |-id=Berkelium-251m | style="text-indent:1em" | 251mBk | colspan="3" style="text-indent:2em" | 35.5(13) keV | Script error: No such module "val". | IT | 251Bk | (7/2+) |-id=Berkelium-252 | 252Bk | style="text-align:right" | 97 | style="text-align:right" | 155 | 252.08431(22)# | Script error: No such module "val". | β | 252Cf | |-id=Berkelium-253 | 253Bk | style="text-align:right" | 97 | style="text-align:right" | 156 | 253.08688(39)# | 60# min | β? | 253Cf | 3/2-# Template:Isotopes table/footer

Actinides vs fission products

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Actinides[1] by decay chain Half-life
range (a)
Fission products of 235U by yield[2]
4n 4n + 1 4n + 2 4n + 3 4.5–7% 0.04–1.25% <0.001%
228Ra 4–6 a 155Euþ
248Bk[3] > 9 a
244Cmƒ 241Puƒ 250Cf 227Ac 10–29 a 90Sr 85Kr 113mCdþ
232Uƒ 238Puƒ 243Cmƒ 29–97 a 137Cs 151Smþ 121mSn
249Cfƒ 242mAmƒ 141–351 a

No fission products have a half-life
in the range of 100 a–210 ka ...

241Amƒ 251Cfƒ[4] 430–900 a
226Ra 247Bk 1.3–1.6 ka
240Pu 229Th 246Cmƒ 243Amƒ 4.7–7.4 ka
245Cmƒ 250Cm 8.3–8.5 ka
239Puƒ 24.1 ka
230Th 231Pa 32–76 ka
236Npƒ 233Uƒ 234U 150–250 ka 99Tc 126Sn
248Cm 242Pu 327–375 ka 79Se
1.33 Ma 135Cs
237Npƒ 1.61–6.5 Ma 93Zr 107Pd
236U 247Cmƒ 15–24 Ma 129I
244Pu 80 Ma

... nor beyond 15.7 Ma[5]

232Th 238U 235Uƒ№ 0.7–14.1 Ga
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References

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  1. Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
  2. Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
  3. Script error: No such module "Citation/CS1".
    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 [years]. No growth of Cf248 was detected, and a lower limit for the β half-life can be set at about 104 [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]."
  4. This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
  5. Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is eight quadrillion years.

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