Fluoromethylidyne

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Fluoromethylidyne
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Molar mass 31.0091 g mol−1

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Fluoromethylidyne is not a stable chemical species but a metastable radical containing one highly reactive carbon atom bound to one fluorine atom with the formula CF.[1] The carbon atom has a lone-pair and a single unpaired (radical) electron in the ground state.[2]

Ground-state fluoromethylidyne radicals can be produced by the ultraviolet photodissociation of dibromodifluoromethane at 248 nanometer wavelength.[3]

It readily and irreversibly dimerises to difluoroacetylene, also known as difluoroethyne, perfluoroacetylene, or di- or perfluoroethylyne. Under certain conditions it can hexamerise to hexafluorobenzene.

See also

References

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