Dicarbonate
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| MeSH | pyrocarbonate |
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A dicarbonate, also known as a pyrocarbonate, is a chemical containing the divalent Template:Chem2 or Template:Chem2 functional group, which consists of two carbonate groups sharing an oxygen atom. It is one of polycarbonate functional groups. These compounds can be viewed as derivatives of the hypothetical compound dicarbonic acid,[2] Template:Chem2 or Template:Chem2. Three important organic compounds containing this group are:
- dimethyl dicarbonate Template:Chem2
- diethyl dicarbonate Template:Chem2
- di-tert-butyl dicarbonate Template:Chem2, also known as Boc anhydride.
It is one of the oxocarbon anions, consisting solely of oxygen and carbon. The anion has the formula Template:Chem2 or Template:Chem2. Dicarbonate salts are apparently unstable at ambient conditions, but can be made under pressure and may have a fleeting existence in carbonate solutions.[3]
The term dicarbonate is sometimes used erroneously to refer to bicarbonate, the common name of the hydrogencarbonate anion Template:Chem2 or esters of the hydrogencarbonate functional group Template:Chem2. It is also sometimes used for chemicals that contain two carbonate units in their covalent structure or stoichiometric formula.
Inorganic salts
Template:Chem2 (lead(II) dicarbonate) can be formed at 30 GPa and 2000K from PbCO3 and CO2. It forms white monoclinic crystals, with space group P21/c and four formula units per unit cell. At 30 GPa the unit cell has a=4.771 b=8.079 c=7.070 Å and β=91.32°. The unit cell volume is 272.4 Å3 and density 7.59.[4]
Template:Chem2 (strontium dicarbonate) is very similar to the lead compound, and also has monoclinic structure with space group P21/c and four formula units per unit cell. At 30 GPa the unit cell has a=4.736 b=8.175 c=7.140 Å and β=91.34°. The unit cell volume is 276.3 Å3 and density 4.61.[4] The double Sr=O bonds have lengths of 1.22, 1.24, and 1.25 Å. The single Sr-O bonds have lengths of 1.36 and 1.41 Å. The angles subtended at the carbon atoms are slightly less than 120°, and the angle at the C-O-C is larger.[5]
See also
- Tricarbonate
- Peroxodicarbonate
- Oxalate
- Pyrosulfate
- Peroxydisulfate
- Dithionate
- Trithionate
- Tetrathionate
- Pyrophosphate
- Polyphosphate
References
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