Carbon tetroxide
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Carbon tetroxide or Oxygen carbonate (in its C2v isomer) is a highly unstable oxide of carbon with formula Template:Chem/link. It was proposed as an intermediate in the O-atom exchange between carbon dioxide (Template:Chem/link) and oxygen (Template:Chem/link) at high temperatures.[1] The C2v isomer, which is 138 kJ mol−1 more stable than the D2d isomer, was first detected in electron-irradiated ices of carbon dioxide via infrared spectroscopy.[2]
The isovalent carbon tetrasulfide CS4 is also known from inert gas matrix. It has D2d symmetry with the same atomic arrangement as CO4 (D2d).[3]
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