Carbon nitride
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Carbon nitrides are organic compounds consisting only of carbon and nitrogen atoms.
Covalent network compounds
These materials are organic semiconductors. Due to its hydrogen-bonding motifs and electron-rich properties, this carbon material is considered a potential candidate for material applications in carbon supplementation.[1]
- Beta carbon nitride - a solid with a formula Template:Chem2, which is predicted to be harder than diamond.
- Graphitic carbon nitride - Template:Chem2, with important catalytic and sensor properties.[2]
- Dicyanodiazomethane Template:Chem2, the only Template:Chem2 isomer studied experimentally
- Tricyanamide Template:Chem2 - Template:Chem2 monomer (has never been prepared yet)
- Dicyanocarbodiimide Template:Chem2 - another Template:Chem2 monomer (was detected in products of photolysis of triazido-s-triazine).[3]
- Template:Chem2 - a combined triazole and triazine framework.[4]
- MCN-12 (Template:Chem2) and MCN-13 (Template:Chem2).[5]
Azafullerenes
- Azafullerenes are a class of heterofullerenes in which the element substituting for carbon is nitrogen.[6] Examples include Template:Chem2 (biazafullerenyl),[7] Template:Chem2 (diaza[60]fullerene), Template:Chem2 (triaza[60]fullerene) and Template:Chem2.
Cyanofullerenes
- Cyanofullerenes are a class of modified fullerenes in which cyano- groups are attached to a fullerene skeleton. These have the formula Template:Chem2, where n takes the values 1 to 9.
Cyanogen
- Cyanogen - Template:Chem2 (Template:Chem2)
- Isocyanogen - Template:Chem2 (Template:Chem2)
- Diisocyanogen - Template:Chem2 (Template:Chem2)
- Paracyanogen - a cyanogen polymer, Template:Chem2
- Paraisocyanogen - a cyanogen polymer, Template:Chem2
Percyanoalkynes, -alkenes and -alkanes
- dicyanoacetylene - Template:Chem2 or Template:Chem2, also called carbon subnitride or but-2-ynedinitrile
- tetracyanoethylene - Template:Chem2 or Template:Chem2
- tetracyanomethane - Template:Chem2 or Template:Chem2
- 2,2-diisocyanopropanedinitrile - Template:Chem2 or Template:Chem2 also called dicyano(diisocyano)methane
- hexacyanoethane - Template:Chem2 or Template:Chem2
- hexacyanocyclopropane - Template:Chem2 or cyclo-Template:Chem2
- hexacyanobutadiene[8] - Template:Chem2 or Template:Chem2
Dicyanopolyynes
Dicyanopolyynes are compounds with the chemical formula Template:Chem2. They are composed of a chain of carbon atoms with alternating single and triple bonds, terminated by nitrogen atoms. Although not polyynes, cyanogen Template:Chem2 (n = 0) and dicyanoacetylene Template:Chem2 (n = 1) fit within this series.
- Template:Chem2 or Template:Chem2, dicyanobutadiyne or dicyanodiacetylene
- Template:Chem2 or Template:Chem2, dicyanohexatriyne or dicyanotriacetylene
- Template:Chem2 or Template:Chem2, dicyanooxatetrayne or dicyanotetraacetylene
- Template:Chem2 or Template:Chem2, dicyanodecapentayne or dicyanopentaacetylene
- Template:Chem2 or Template:Chem2, dicyanododecahexayne or dicyanohexaacetylene
- Template:Chem2 or Template:Chem2, dicyanotetradecaheptayne or dicyanoheptaacetylene
- Template:Chem2 or Template:Chem2, dicyanohexadecaoctayne or dicyanooctaacetylene
- Template:Chem2 or Template:Chem2, dicyanooctadecanonayne or dicyanononaacetylene
- Template:Chem2 or Template:Chem2, dicyanoicosadecayne or dicyanodecaacetylene
Perazidoalkynes, -alkenes and -alkanes
Percyanoheterocycles
- pentacyanopyridine - Template:Chem2
- tetracyanopyrazine - Template:Chem2
- tricyanotriazine - Template:Chem2[9]
- tetracyano-bitriazine - Template:Chem2[9]
- dicyanotetrazine - Template:Chem2
- hexacyanotrisimidazole - Template:Chem2
- hexacyanohexaazatriphenylene - Template:Chem2
Aromatic cyanocarbons
- hexacyanobenzene - Template:Chem2 or Template:Chem2
- octacyanonaphthalene - Template:Chem2 or Template:Chem2
- decacyanoanthracene - Template:Chem2 or Template:Chem2
Other compounds
- cyanonitrene - Template:Chem2 or Template:Chem2 (one of the nitrogens is univalent)
- azodicarbonitrile - Template:Chem2 or Template:Chem2, cis and trans isomers
- cyanogen azide - Template:Chem2 or Template:Chem2
- 1-diazidocarbamoyl-5-azidotetrazole - Template:Chem2
- 2,2′-azobis(5-azidotetrazole) - Template:Chem2
- triazidotriazine (cyanuric triazide) - Template:Chem2 (Template:Chem2)
- triazidoheptazine - Template:Chem2 (Template:Chem2)
- tricyanomethanimine (dicyanomethylene-cyanamide) - Template:Chem2 or Template:Chem2
- diazidodicyanoethylene - Template:Chem2 or Template:Chem2 and Template:Chem2, cis and trans
- dicyanodiazomethane - Template:Chem2 or Template:Chem2
- Template:Chem name - Template:Chem2 or Template:Chem2 (and isomers cyanoisocyanocarbene Template:Chem2, diisocyanocarbene Template:Chem2, 3-cyano-2H-azirenylidene and 3-isocyano-2H-azirenylidene)
- 1,3,5-triazido-2,4,6-tricyanobenzene - Template:Chem2 (Template:Chem2)
- nitrogen tricyanide Template:Chem2 and carbon bis(cyanamide) Template:Chem2, two formal monomers of polymeric Template:Chem2
Anions and functional groups
- cyanide - Template:Chem2 ion, cyanide Template:Chem2 and isocyanide Template:Chem2 functional groups
- dicyanamide - Template:Chem2 or Template:Chem2
- tricyanomethanide - Template:Chem2 or Template:Chem2
- pentacyanoethanide - Template:Chem2 or Template:Chem2
- pentacyanopropenide (pentacyanoallyl anion) - Template:Chem2
- 2-dicyanomethylene-1,1,3,3-tetracyanopropanediide Template:Chem2
- tricyanomelaminate anion - Template:Chem2
- melonate - Template:Chem2
- Template:Chem name anions - Template:Chem2 (n odd) and Template:Chem2 (n even)
- cyanoacetlyide - Template:Chem2 or Template:Chem2
- cyanobutadiynylide - Template:Chem2 or Template:Chem2
- cyanopolyynide anions - Template:Chem2 (n odd)
See also
References
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- ↑ Sato, T., Narazaki, A., Kawaguchi, Y., Niino, H. and Bucher, G. (2003), Dicyanocarbodiimide and Trinitreno-s-triazine Generated by Consecutive Photolysis of Triazido-s-triazine in a Low-Temperature Nitrogen Matrix†. Angewandte Chemie International Edition, 42: 5206-5209.Script error: No such module "CS1 identifiers".
- ↑ I. Y. Kim, S. Kim, X. Jin, S. Premkumar, G. Chandra, N.-S. Lee, G. P. Mane, S.-J. Hwang, S. Umapathy, A. Vinu, Angew. Chem. Int. Ed. 2018, 57, 17135. Script error: No such module "CS1 identifiers".
- ↑ Kim, I. Y., Kim, S., Premkumar, S., Yang, J.-H., Umapathy, S., Vinu, A., "Thermodynamically Stable Mesoporous C3N7 and C3N6 with Ordered Structure and Their Excellent Performance for Oxygen Reduction Reaction". Small 2020, 16, 1903572. Script error: No such module "CS1 identifiers".
- ↑ D.J. Harris, Discovery of Nitroballs: Research in Fullerene Chemistry, 1993 California State Science Fair, http://www.usc.edu/CSSF/History/1993/S05.html Template:Webarchive
- ↑ Hummelen et al, "Isolation of the Heterofullerene C59N as Its Dimer (C59N)2", Science 269: 1554-1556 (1995). Script error: No such module "CS1 identifiers".
- ↑ O.W.Webster, Hexacyanobutadiene, J. Am. Chem. Soc. 86(14): 2898–2902 (1964)
- ↑ a b Sesto et al, "Chemical Reduction of 2,4,6-Tricyano-1,3,5-triazine and 1,3,5-Tricyanobenzene. Formation of Novel 4,4',6,6'-Tetracyano-2,2'-bitriazine and Its Radical Anion", J. Org. Chem. 68: 3367-3379 (2003). Script error: No such module "CS1 identifiers".
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