Bixin

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Bixin[1]
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Bixin is an apocarotenoid found in the seeds of the achiote tree (Bixa orellana)[2] from which it derives its name. It is commonly extracted from the seeds to form annatto, a natural food coloring, containing about 5% pigments, of which 70–80% are bixin.[3]

Applications

File:Bixa orellana fruit open.jpg
Red seeds of the achiote tree
File:CheetosCrop.jpg
Bixin is one of the colorants used in the snack Cheetos.

Several thousand tons are harvested annually.[4]

Chemical properties

Bixin is unstable. It isomerizes into trans-bixin (β-bixin), the double-bond isomer.[1]

File:Trans-bixin.png
Chemical structure of trans-bixin

Bixin is soluble in fats and alcohols but insoluble in water. Upon exposure to alkali, the methyl ester is hydrolyzed to produce the dicarboxylic acid norbixin, a water-soluble derivative.

File:Norbixin structure.png
Chemical structure of norbixin

References

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  1. a b Merck Index, 11th Edition, 1320
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  3. Executive Summary Bixin Script error: No such module "webarchive"., National Toxicology Program
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