Amyl alcohol

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Template:Short description Template:More refs Amyl alcohols are alcohols with the formula C5H11OH.[1] Eight are known. A mixture of amyl alcohols (also called amyl alcohol) can be obtained from fusel alcohol. Amyl alcohol is used as a solvent and in esterification, by which is produced amyl acetate and other products. The name amyl alcohol without further specification applies to the normal (straight-chain) form, 1-pentanol.[2]

Amyl alcohol isomers
Common name Structure Type IUPAC name Boiling point (°C)[3]
1-pentanol
or normal amyl alcohol
File:Pentan-1-ol-2D-skeletal.png primary Pentan-1-ol 138.5
2-methyl-1-butanol
or active amyl alcohol
File:2-Methyl-1-butanol.svg primary 2-Methylbutan-1-ol 128.7
3-methyl-1-butanol
or isoamyl alcohol
or isopentyl alcohol
File:Isoamyl alcohol.svg primary 3-Methylbutan-1-ol 131.2
2,2-dimethyl-1-propanol
or neopentyl alcohol
File:Neopentyl-alcohol-2D-skeletal.svg primary 2,2-Dimethylpropan-1-ol 113.1
2-pentanol
or sec-amyl alcohol
or methyl (n) propyl carbinol
File:Pentan-2-ol-2D-skeletal.png secondary Pentan-2-ol 118.8
3-methyl-2-butanol
or sec-isoamyl alcohol
or methyl isopropyl carbinol
File:3-methylbutan-2-ol-2D-skeletal.png secondary 3-Methylbutan-2-ol 113.6
3-Pentanol File:Pentan-3-ol-2D-skeletal.png secondary Pentan-3-ol 115.3
2-methyl-2-butanol
or tert-amyl alcohol
File:Tert-pentyl-alcohol-2D-skeletal.svg tertiary 2-Methylbutan-2-ol 102

Three of these alcohols, 2-methyl-1-butanol, 2-pentanol, and 3-methyl-2-butanol (methyl isopropyl carbinol), contain stereocenters, and are therefore chiral and optically active.

The most important amyl alcohol is isoamyl alcohol, the chief one generated by fermentation in the production of alcoholic beverages and a constituent of fusel oil. The other amyl alcohols may be obtained synthetically.

References

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  1. Merriam-Webster's Collegiate Dictionary 11th Ed. 2004
  2. Script error: No such module "citation/CS1".
  3. Calculated boiling points from ChemSpider.