1-Pentanol

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1-Pentanol
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Template:Longitem 1730975
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Template:Longitem 25922
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MeSH n-Pentanol
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UN number 1105
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Template:Longitem Template:Chembox Elements/molecular formula
Molar mass Template:Chem molar mass
Density 0.811 g cm−3
Melting point Template:Chembox CalcTemperatures
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log P 1.348
Vapor pressure 200 Pa (at 20 °C)
Template:Longitem −67.7·10−6 cm3/mol
Template:Longitem 1.409
Template:Longitem 207.45 J K−1 mol−1
Template:Longitem 258.9 J K−1 mol−1
Template:Longitem −351.90–−351.34 kJ mol−1
Template:Longitem −3331.19–−3330.63 kJ mol−1
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Template:Longitem Hexane

Pentylamine

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1-Pentanol, (or n-pentanol, pentan-1-ol), is an organic compound with the formula Template:Chem2 and is classified as a primary alcohol.[2] It is a colourless liquid with a distinctive aroma. It is one of 8 isomeric alcohols with the formula Template:Chem2. It is used as a solvent, a biological drying agent and in the synthesis of some fragrance compounds. It is also a common component of fusel alcohols (fusel oils), the undesirable byproducts of alcoholic fermentation.

Preparation

1-Pentanol is prepared from 1-butene by hydroformylation followed by hydrogenation of the resulting pentanal.[3]

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Pentanol can be prepared by fractional distillation of fusel oil. To reduce the use of fossil fuels, research is underway to develop cost-effective methods of producing (chemically identical) bio-pentanol with fermentation.[4][5]

Uses and occurrence

The hydroxyl group (OH) is the active site of many reactions. The ester formed from 1-pentanol and butyric acid is pentyl butyrate, which has an apricot-like odor. The ester formed from 1-pentanol and acetic acid is amyl acetate (also called pentyl acetate), which has a banana-like odor.

It is a precursor to dipentyl zinc dithiophosphates, which are used in froth flotation.[3]

In 2014, a study was conducted comparing the performance of diesel fuel blends with various proportions of pentanol as an additive. While gaseous emissions increased with higher concentrations of pentanol, particulate emissions decreased.[6]

Pentanol is often used as a solvent.

References

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  2. CRC Handbook of Chemistry and Physics 65th ed.
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  6. Wei, Liangjie & Cheung, C.s & Huang, Zuohua. (2014). Effect of n-pentanol addition on the combustion, performance and emission characteristics of a direct-injection diesel engine. Energy. 70. 10.1016/j.energy.2014.03.106.

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