Titanium(III) fluoride
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| Template:Longitem | TiF3 |
| Molar mass | 104.862 g/mol |
| Appearance | violet to purple-red powder |
| Density | 2.98 g/cm3 |
| Melting point | Template:Chembox CalcTemperatures |
| Boiling point | Template:Chembox CalcTemperatures |
| Template:Longitem | +1300·10−6 cm3/mol |
| Template:Longitem | Rhombohedral, hR24 |
| Template:Longitem | R-3c, No. 167 |
| Template:Longitem | Titanium(III) bromide Titanium(III) chloride Titanium(III) iodide |
| Template:Longitem | Titanium(IV) fluoride |
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Titanium(III) fluoride is the inorganic compound with the formula TiF3. A violet, paramagnetic solid, it is one of two titanium fluorides, the other being titanium tetrafluoride.[1] It adopts a defect perovskite-like structure such that each Ti center has octahedral coordination geometry, and each fluoride ligand is doubly bridging.[2]
Titanium(III) fluoride can be prepared by dissolution of titanium metal in hydrogen fluoride. In air, it slowly oxidizes to titanium(IV).[1]
References
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