Tin(IV) sulfide

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Tin(IV) sulfide is a compound with the formula Template:Chem. A brown, water-insoluble solid, it is a semiconductor with band gap 2.2 eV.[1] It occurs naturally as the rare mineral berndtite.[2]

Synthesis and structure

File:SnS2-bas.png
Fragment of the SnS2 lattice. Color code: yellow = S, gray = Sn.

The compound precipitates as a brown solid upon the addition of Template:Chem to solutions containing tin(IV) species. This reaction is reversed at low pH. It can also be prepared by heating finely ground Sn with excess sulfur.[3]

The compound crystallizes in the cadmium iodide motif, with the Sn(IV) situated in "octahedral holes' defined by six sulfide centers.[4]

The material reacts with sulfide salts to give a series of thiostannates with the formula Template:Chem.[5] A simplified equation for this depolymerization reaction is:

Template:Chem + Template:ChemTemplate:SfracTemplate:Chem

Potential uses

Crystalline Template:Chem has a bronze color and is used in decorative coating[6] where it is known as mosaic gold.

Tin (IV) sulfide has various uses in electrochemistry. It serves as an anode in prototypes of lithium-ion batteries.[7] Intercalation with organometallic reagents is reversible.[8]

It has also been evaluated as a component of supercapacitors, which could be used for energy storage.[9]

See also

References

Template:Reflist

External links

Template:Sister project

Template:Tin compounds Template:Sulfides

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  2. Vaughan, D. J.; Craig, J. R. "Mineral Chemistry of Metal Sulfides" Cambridge University Press, Cambridge: 1978. Template:ISBN.
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  4. Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. Template:ISBN.
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  6. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. Template:ISBN.
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