List of thermodynamic properties

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Template:Short description

In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state. Some constants, such as the ideal gas constant, Template:Mvar, do not describe the state of a system, and so are not properties. On the other hand, some constants, such as Template:Mvar (the freezing point depression constant, or cryoscopic constant), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties.

"Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive or extensive).

Regarding work and heat

Work and heat are not thermodynamic properties, but rather process quantities: flows of energy across a system boundary. Systems do not contain work, but can perform work, and likewise, in formal thermodynamics, systems do not contain heat, but can transfer heat. Informally, however, a difference in the energy of a system that occurs solely because of a difference in its temperature is commonly called heat, and the energy that flows across a boundary as a result of a temperature difference is "heat".

Altitude (or elevation) is usually not a thermodynamic property. Altitude can help specify the location of a system, but that does not describe the state of the system. An exception would be if the effect of gravity need to be considered in order to describe a state, in which case altitude could indeed be a thermodynamic property.

Thermodynamic properties and their characteristics
Property Symbol Units Extensive? Intensive? Conjugate Potential?
Activity Template:Mvar Template:Spaced ndash Green tickY
Chemical potential Template:Mvar kJ/mol Green tickY Particle
number Template:Mvar
Compressibility (adiabatic) Template:Mvar, Template:Mvar Pa−1 Green tickY
Compressibility (isothermal) Template:Mvar, Template:Mvar Pa−1 Green tickY
Cryoscopic constant[1] Template:Mvar K·kg/mol Green tickY
Density Template:Mvar kg/m3 Green tickY
Ebullioscopic constant Template:Mvar K·kg/mol Green tickY
Enthalpy Template:Mvar J Green tickY Green tickY
Script error: No such module "String". Specific enthalpy Template:Mvar J/kg Green tickY
Entropy Template:Mvar J/K Green tickY Temperature Template:Mvar Green tickY (entropic)
Script error: No such module "String". Specific entropy Template:Mvar J/(kg K) Green tickY
Fugacity Template:Mvar N/m2 Green tickY
Gibbs free energy Template:Mvar J Green tickY Green tickY
Script error: No such module "String". Specific Gibbs free energy Template:Mvar J/kg Green tickY
Gibbs free entropy ΞScript error: No such module "Check for unknown parameters". J/K Green tickY Green tickY (entropic)
Grand / Landau potential ΩScript error: No such module "Check for unknown parameters". J Green tickY Green tickY
Heat capacity (constant pressure) Template:Mvar J/K Green tickY
Script error: No such module "String". Specific heat capacity
Script error: No such module "String".(constant pressure)
Template:Mvar J/(kg·K) Green tickY
Heat capacity (constant volume) Template:Mvar J/K Green tickY
Script error: No such module "String". Specific heat capacity
Script error: No such module "String".(constant volume)
Template:Mvar J/(kg·K) Green tickY
Helmholtz free energy Template:Mvar, Template:Mvar J Green tickY Green tickY
Helmholtz free entropy ΦScript error: No such module "Check for unknown parameters". J/K Green tickY Green tickY (entropic)
Internal energy Template:Mvar J Green tickY Green tickY
Script error: No such module "String". Specific internal energy Template:Mvar J/kg Green tickY
Internal pressure Template:Mvar Pa Green tickY
Mass Template:Mvar kg Green tickY
Particle number Template:Mvar Template:Spaced ndash Green tickY Chemical
potential Template:Mvar
Pressure Template:Mvar Pa Green tickY Volume Template:Mvar
Temperature Template:Mvar K Green tickY Entropy Template:Mvar
Thermal conductivity Template:Mvar W/(m·K) Green tickY
Thermal diffusivity Template:Mvar m2/s Green tickY
Thermal expansion (linear) Template:Mvar K−1 Green tickY
Thermal expansion (area) Template:Mvar K−1 Green tickY
Thermal expansion (volumetric) Template:Mvar K−1 Green tickY
Vapor quality[2] Template:Mvar Template:Spaced ndash Green tickY
Volume Template:Mvar m3 Green tickY Pressure Template:Mvar
Script error: No such module "String". Specific volume Template:Mvar m3/kg Green tickY

See also

References

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