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|ImageFile1 = Sodium_bis(trimethylsilyl)amide.png |ImageFile2 = Cyclic Trimer of Sodium bis(trimethylsilyl)amide Structural formula V1.svg ...

...es, such as [[sodium bis(trimethylsilyl)amide|sodium]] and [[potassium bis(trimethylsilyl)amide]] (NaHMDS and KHMDS, respectively) ...

|ImageNameL1 = Structural formula of bis(trimethylsilyl)amine |ImageNameR1 = Spacefill model of bis(trimethylsilyl)amine ...

...tinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides|journal=Journal of the Chemical Society, Dalton Transact ...lume = 5 | pages = 1285 | title = Synthesis and x-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C<sub>5</ ...

...hesized by treating acyl anion equivalents with silyl halides (typically [[trimethylsilyl chloride]], tmsCl). Silylation of 2-lithio-[[1,3-dithiane]], followed by h Tertiary amides react with silyl lithium reagents: ...

...ef>{{cite journal |language=en |title=Condensations Effected by the Alkali Amides. IV. The Reactions of Esters with Lithium Amide and Certain Substituted Lit ...ser, C. L. |title=Efficient Synthesis of Halomethyl-2,2'-Bipyridines: 4,4'-Bis(chloromethyl)-2,2'-Bipyridine |collvol=10 |collvolpages=107 |year=2004 |pre ...

...]|year=2002|volume=647|pages=50–60|doi=10.1016/S0022-328X(01)01433-4|title=Bis(pentafluorophenyl)mercury—a versatile synthon in organo-, organooxo-, and o ...lates and new methods for corresponding aryl oxides and bis(trimethylsilyl)amides|first1=Bekir|last2=Hitchcock|first2=Peter B.|last3=Lappert|first3=Michael F ...

* Refluxing with [[Trimethylsilyl chloride|TMSCl]], [[sodium iodide]] and [[acetonitrile]]<ref>{{Cite journal ...ther.|date=1972-06-01|title=Reductive cleavage of sulfonamides with sodium bis(2-methoxyethoxy)aluminum hydride|url=https://doi.org/10.1021/jo00978a034|jo ...

|IUPACName = Sodium amide, sodium azanide<ref>{{GoldBookRef |title=amides |file=A00266}}</ref> |OtherAnions = [[Sodium bis(trimethylsilyl)amide]] ...

...1">{{cite journal | author=H.A. Staab | title=Syntheses Using Heterocyclic Amides (Azolides) | journal=Angewandte Chemie International Edition in English | v ...ole requires more preparative effort with the advantage that the coproduct trimethylsilyl chloride is volatile. ...

...elenium tetrachloride]] (SeCl₄) with [[Metal bis(trimethylsilyl)amides|{{chem|[((CH|3|)|3|Si)|2|N]|2|Se}}]].<ref>{{cite journal |doi=10.1021/ic000 ...

...late, whilst reaction at &minus;78&nbsp;°C with [[Metal bis(trimethylsilyl)amides|potassium hexamethyldisilazide]], {{chem|KN[Si(CH|3|)|3|]|2}} and triethylb ...

...:Triphosgen Strukturformel.svg|90px|triphosgene]]<br>[[Triphosgene]]<br>''(bis(trichloromethyl) carbonate)'' ...|| RB(OR)₂ || [[File:Boronate-ester-2D.svg|75px|center]] || O-[bis(alkoxy)alkylboronyl]- || ''substituent''<br>'''boronic acid'''<br>di(''subs ...

...catalyst improvements in the hetero cross-coupling of aryl halides and tin amides|author1=Paul,F. |author2=Patt, J. |author3=Hartwig, J.F. | ...s for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Cataly ...

...d structure of an LDA-THF complex |doi=10.1021/jo00053a001}}</ref> Lithium amides adopt polymeric-ladder type structures in non-coordinating solvent in the s ...nder | first2 = Johan | chapter = Structure and dynamics of chiral lithium amides| title = PATAI'S Chemistry of Functional Groups.| publisher = John Wiley & ...

[[File:Tms_protecting.svg|thumb|Trimethylsilyl chloride, activated with imidazole, protects a secondary alcohol]] ...ne]] (TMS-Cl), a [[Müller-Rochow synthesis|Direct Process]] byproduct. The trimethylsilyl ethers are also extremely sensitive to acid hydrolysis (for example [[silic ...

...cyanation of alkenes. O-Silyl cyanohydrins are generated by the addition [[trimethylsilyl cyanide]] in the presence of a catalyst (silylcyanation). Cyanohydrins are ===Dehydration of amides=== ...

...l derivatives of acidic hydrogen of other acids are esters as well (e.g. [[amides]]), but not according to the [[IUPAC]].<ref name=iupac>{{GoldBookRef|title= ...ng point) and more volatile (lower boiling point) than the corresponding [[amides]].<ref name=March>March, J. ''Advanced Organic Chemistry'' 4th Ed. J. Wiley ...

*[[Lithium bis(trimethylsilyl)amide]] {{chem|[(CH|3|)|3|Si]|2|NLi}} ...

...tylene]]:<ref name=Bertrand4>{{cite journal|title = Analogous α,α{{prime}}-bis-carbenoid, triply bonded species: synthesis of a stable λ³-phosp [[File:Bis(diisopropylamino)carbene.png|left|thumb|120px|Bis(diisopropylamino) carbene, the first acyclic stable carbene.]] ...