Cross section (physics)
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In physics, the cross section is a measure of the probability that a specific process will take place in a collision of two particles. For example, the Rutherford cross-section is a measure of probability that an alpha particle will be deflected by a given angle during an interaction with an atomic nucleus. Cross section is typically denoted σScript error: No such module "Check for unknown parameters". (sigma) and is expressed in units of area, more specifically in barns. In a way, it can be thought of as the size of the object that the excitation must hit in order for the process to occur, but more exactly, it is a parameter of a stochastic process.
When two discrete particles interact in classical physics, their mutual cross section is the area transverse to their relative motion within which they must meet in order to scatter from each other. If the particles are hard inelastic spheres that interact only upon contact, their scattering cross section is related to their geometric size. If the particles interact through some action-at-a-distance force, such as electromagnetism or gravity, their scattering cross section is generally larger than their geometric size.
When a cross section is specified as the differential limit of a function of some final-state variable, such as particle angle or energy, it is called a differential cross section (see detailed discussion below). When a cross section is integrated over all scattering angles (and possibly other variables), it is called a total cross section or integrated total cross section. For example, in Rayleigh scattering, the intensity scattered at the forward and backward angles is greater than the intensity scattered sideways, so the forward differential scattering cross section is greater than the perpendicular differential cross section, and by adding all of the infinitesimal cross sections over the whole range of angles with integral calculus, we can find the total cross section.
Scattering cross sections may be defined in nuclear, atomic, and particle physics for collisions of accelerated beams of one type of particle with targets (either stationary or moving) of a second type of particle. The probability for any given reaction to occur is in proportion to its cross section. Thus, specifying the cross section for a given reaction is a proxy for stating the probability that a given scattering process will occur.
The measured reaction rate of a given process depends strongly on experimental variables such as the density of the target material, the intensity of the beam, the detection efficiency of the apparatus, or the angle setting of the detection apparatus. However, these quantities can be factored away, allowing measurement of the underlying two-particle collisional cross section.
Differential and total scattering cross sections are among the most important measurable quantities in nuclear, atomic, and particle physics.
With light scattering off of a particle, the cross section specifies the amount of optical power scattered from light of a given irradiance (power per area). Although the cross section has the same units as area, the cross section may not necessarily correspond to the actual physical size of the target given by other forms of measurement. It is not uncommon for the actual cross-sectional area of a scattering object to be much larger or smaller than the cross section relative to some physical process. For example, plasmonic nanoparticles can have light scattering cross sections for particular frequencies that are much larger than their actual cross-sectional areas.
Collision among gas particles
In a gas of finite-sized particles there are collisions among particles that depend on their cross-sectional size. The average distance that a particle travels between collisions depends on the density of gas particles. These quantities are related by
where
- σScript error: No such module "Check for unknown parameters". is the cross section of a two-particle collision (SI unit: m2),
- λScript error: No such module "Check for unknown parameters". is the mean free path between collisions (SI unit: m),
- nScript error: No such module "Check for unknown parameters". is the number density of the target particles (SI unit: m−3).
If the particles in the gas can be treated as hard spheres of radius rScript error: No such module "Check for unknown parameters". that interact by direct contact, as illustrated in Figure 1, then the effective cross section for the collision of a pair is
If the particles in the gas interact by a force with a larger range than their physical size, then the cross section is a larger effective area that may depend on a variety of variables such as the energy of the particles.
Cross sections can be computed for atomic collisions but also are used in the subatomic realm. For example, in nuclear physics a "gas" of low-energy neutrons collides with nuclei in a reactor or other nuclear device, with a cross section that is energy-dependent and hence also with well-defined mean free path between collisions.
Attenuation of a beam of particles
Script error: No such module "Labelled list hatnote". If a beam of particles enters a thin layer of material of thickness dzScript error: No such module "Check for unknown parameters"., the flux ΦScript error: No such module "Check for unknown parameters". of the beam will decrease by dΦScript error: No such module "Check for unknown parameters". according to
where σScript error: No such module "Check for unknown parameters". is the total cross section of all events, including scattering, absorption, or transformation to another species. The volumetric number density of scattering centers is designated by nScript error: No such module "Check for unknown parameters".. Solving this equation exhibits the exponential attenuation of the beam intensity:
where Φ0Script error: No such module "Check for unknown parameters". is the initial flux, and zScript error: No such module "Check for unknown parameters". is the total thickness of the material. For light, this is called the Beer–Lambert law.
Differential cross section
Consider a classical measurement where a single particle is scattered off a single stationary target particle. Conventionally, a spherical coordinate system is used, with the target placed at the origin and the zScript error: No such module "Check for unknown parameters". axis of this coordinate system aligned with the incident beam. The angle θScript error: No such module "Check for unknown parameters". is the scattering angle, measured between the incident beam and the scattered beam, and the φScript error: No such module "Check for unknown parameters". is the azimuthal angle.
The impact parameter bScript error: No such module "Check for unknown parameters". is the perpendicular offset of the trajectory of the incoming particle, and the outgoing particle emerges at an angle θScript error: No such module "Check for unknown parameters".. For a given interaction (coulombic, magnetic, gravitational, contact, etc.), the impact parameter and the scattering angle have a definite one-to-one functional dependence on each other. Generally the impact parameter can neither be controlled nor measured from event to event and is assumed to take all possible values when averaging over many scattering events. The differential size of the cross section is the area element in the plane of the impact parameter, i.e. dσ = b dφ dbScript error: No such module "Check for unknown parameters".. The differential angular range of the scattered particle at angle θScript error: No such module "Check for unknown parameters". is the solid angle element dΩ = sin θ dθ dφScript error: No such module "Check for unknown parameters".. The differential cross section is the quotient of these quantities, Template:SfracScript error: No such module "Check for unknown parameters"..
It is a function of the scattering angle (and therefore also the impact parameter), plus other observables such as the momentum of the incoming particle. The differential cross section is always taken to be positive, even though larger impact parameters generally produce less deflection. In cylindrically symmetric situations (about the beam axis), the azimuthal angle φScript error: No such module "Check for unknown parameters". is not changed by the scattering process, and the differential cross section can be written as
- .
In situations where the scattering process is not azimuthally symmetric, such as when the beam or target particles possess magnetic moments oriented perpendicular to the beam axis, the differential cross section must also be expressed as a function of the azimuthal angle.
For scattering of particles of incident flux FincScript error: No such module "Check for unknown parameters". off a stationary target consisting of many particles, the differential cross section Template:SfracScript error: No such module "Check for unknown parameters". at an angle (θ,φ)Script error: No such module "Check for unknown parameters". is related to the flux of scattered particle detection Fout(θ,φ)Script error: No such module "Check for unknown parameters". in particles per unit time by
Here ΔΩScript error: No such module "Check for unknown parameters". is the finite angular size of the detector (SI unit: sr), nScript error: No such module "Check for unknown parameters". is the number density of the target particles (SI unit: m−3), and tScript error: No such module "Check for unknown parameters". is the thickness of the stationary target (SI unit: m). This formula assumes that the target is thin enough that each beam particle will interact with at most one target particle.
The total cross section σScript error: No such module "Check for unknown parameters". may be recovered by integrating the differential cross section Template:SfracScript error: No such module "Check for unknown parameters". over the full solid angle (4πScript error: No such module "Check for unknown parameters". steradians):
It is common to omit the "differential" qualifier when the type of cross section can be inferred from context. In this case, σScript error: No such module "Check for unknown parameters". may be referred to as the integral cross section or total cross section. The latter term may be confusing in contexts where multiple events are involved, since "total" can also refer to the sum of cross sections over all events.
The differential cross section is extremely useful quantity in many fields of physics, as measuring it can reveal a great amount of information about the internal structure of the target particles. For example, the differential cross section of Rutherford scattering provided strong evidence for the existence of the atomic nucleus.
Instead of the solid angle, the momentum transfer may be used as the independent variable of differential cross sections.
Differential cross sections in inelastic scattering contain resonance peaks that indicate the creation of metastable states and contain information about their energy and lifetime.
Quantum scattering
In the time-independent formalism of quantum scattering, the initial wave function (before scattering) is taken to be a plane wave with definite momentum kScript error: No such module "Check for unknown parameters".:
where zScript error: No such module "Check for unknown parameters". and rScript error: No such module "Check for unknown parameters". are the relative coordinates between the projectile and the target. The arrow indicates that this only describes the asymptotic behavior of the wave function when the projectile and target are too far apart for the interaction to have any effect.
After scattering takes place it is expected that the wave function takes on the following asymptotic form:
where fScript error: No such module "Check for unknown parameters". is some function of the angular coordinates known as the scattering amplitude. This general form is valid for any short-ranged, energy-conserving interaction. It is not true for long-ranged interactions, so there are additional complications when dealing with electromagnetic interactions.
The full wave function of the system behaves asymptotically as the sum
The differential cross section is related to the scattering amplitude:
This has the simple interpretation as the probability density for finding the scattered projectile at a given angle.
A cross section is therefore a measure of the effective surface area seen by the impinging particles, and as such is expressed in units of area. The cross section of two particles (i.e. observed when the two particles are colliding with each other) is a measure of the interaction event between the two particles. The cross section is proportional to the probability that an interaction will occur; for example in a simple scattering experiment the number of particles scattered per unit of time (current of scattered particles IrScript error: No such module "Check for unknown parameters".) depends only on the number of incident particles per unit of time (current of incident particles IiScript error: No such module "Check for unknown parameters".), the characteristics of target (for example the number of particles per unit of surface NScript error: No such module "Check for unknown parameters".), and the type of interaction. For Nσ ≪ 1Script error: No such module "Check for unknown parameters". we have
Relation to the S-matrix
If the reduced masses and momenta of the colliding system are miScript error: No such module "Check for unknown parameters"., piScript error: No such module "Check for unknown parameters". and mfScript error: No such module "Check for unknown parameters"., pfScript error: No such module "Check for unknown parameters". before and after the collision respectively, the differential cross section is given byScript error: No such module "Unsubst".
where the on-shell TScript error: No such module "Check for unknown parameters". matrix is defined by
in terms of the S-matrix. Here δScript error: No such module "Check for unknown parameters". is the Dirac delta function. The computation of the S-matrix is the main goal of the scattering theory.
Scattering off solid sphere and off spherical shell
Consider spheres of radius . Classically the cross section would be . Quantum mechanically and for slow particles (i.e. for those whose de Broglie wave length is much larger than the dimensions of the scatterer) and waves the total cross section is . For fast particles higher angular momenta have to be taken into account and the total cross section is approximately . In the case of a spherical shell (potential a delta function) the total cross section allows resonances to appear.[1]
Units
Although the SI unit of total cross sections is m2, a smaller unit is usually used in practice.
In nuclear and particle physics, the conventional unit is the barn b, where 1 b = 10−28 m2 = 100 fm2.[2] Smaller prefixed units such as mb and μb are also widely used. Correspondingly, the differential cross section can be measured in units such as mb/sr.
When the scattered radiation is visible light, it is conventional to measure the path length in centimetres. To avoid the need for conversion factors, the scattering cross section is expressed in cm2, and the number concentration in cm−3. The measurement of the scattering of visible light is known as nephelometry, and is effective for particles of 2–50 μm in diameter: as such, it is widely used in meteorology and in the measurement of atmospheric pollution.
The scattering of X-rays can also be described in terms of scattering cross sections, in which case the square ångström is a convenient unit: 1 Å2 = 10−20 m2 = Script error: No such module "val". = 108 b. The sum of the scattering, photoelectric, and pair-production cross-sections (in barns) is charted as the "atomic attenuation coefficient" (narrow-beam), in barns.[3]
Scattering of light
For light, as in other settings, the scattering cross section for particles is generally different from the geometrical cross section of the particle, and it depends upon the wavelength of light and the permittivity, shape, and size of the particle. The total amount of scattering in a sparse medium is proportional to the product of the scattering cross section and the number of particles present.
In the interaction of light with particles, many processes occur, each with their own cross sections, including absorption, scattering, and photoluminescence. The sum of the absorption and scattering cross sections is sometimes referred to as the attenuation or extinction cross section.
The total extinction cross section is related to the attenuation of the light intensity through the Beer–Lambert law, which says that attenuation is proportional to particle concentration:
where AλScript error: No such module "Check for unknown parameters". is the attenuation at a given wavelength λScript error: No such module "Check for unknown parameters"., CScript error: No such module "Check for unknown parameters". is the particle concentration as a number density, and lScript error: No such module "Check for unknown parameters". is the path length. The absorbance of the radiation is the logarithm (decadic or, more usually, natural) of the reciprocal of the transmittance Template:Mathcal:[4]
Combining the scattering and absorption cross sections in this manner is often necessitated by the inability to distinguish them experimentally, and much research effort has been put into developing models that allow them to be distinguished, the Kubelka-Munk theory being one of the most important in this area.
Cross section and Mie theory
Cross sections commonly calculated using Mie theory include efficiency coefficients for extinction , scattering , and Absorption cross sections. These are normalized by the geometrical cross sections of the particle as The cross section is defined by
where is the energy flow through the surrounding surface, and is the intensity of the incident wave. For a plane wave the intensity is going to be , where is the impedance of the host medium.
The main approach is based on the following. Firstly, we construct an imaginary sphere of radius (surface ) around the particle (the scatterer). The net rate of electromagnetic energy crosses the surface is
where is the time averaged Poynting vector. If energy is absorbed within the sphere, otherwise energy is being created within the sphere. We will not consider this case here. If the host medium is non-absorbing, the energy must be absorbed by the particle. We decompose the total field into incident and scattered parts , and the same for the magnetic field . Thus, we can decompose into the three terms , where
where , , and .
All the field can be decomposed into the series of vector spherical harmonics (VSH). After that, all the integrals can be taken. In the case of a uniform sphere of radius , permittivity , and permeability , the problem has a precise solution.[5] The scattering and extinction coefficients are Where . These are connected as
Dipole approximation for the scattering cross section
Let us assume that a particle supports only electric and magnetic dipole modes with polarizabilities and (here we use the notation of magnetic polarizability in the manner of Bekshaev et al.[6][7] rather than the notation of Nieto-Vesperinas et al.[8]) expressed through the Mie coefficients as Then the cross sections are given by and, finally, the electric and magnetic absorption cross sections are and
For the case of a no-inside-gain particle, i.e. no energy is emitted by the particle internally (), we have a particular case of the Optical theorem Equality occurs for non-absorbing particles, i.e. for .
Scattering of light on extended bodies
In the context of scattering light on extended bodies, the scattering cross section, σscScript error: No such module "Check for unknown parameters"., describes the likelihood of light being scattered by a macroscopic particle. In general, the scattering cross section is different from the geometrical cross section of a particle, as it depends upon the wavelength of light and the permittivity in addition to the shape and size of the particle. The total amount of scattering in a sparse medium is determined by the product of the scattering cross section and the number of particles present. In terms of area, the total cross section (σScript error: No such module "Check for unknown parameters".) is the sum of the cross sections due to absorption, scattering, and luminescence:
The total cross section is related to the absorbance of the light intensity through the Beer–Lambert law, which says that absorbance is proportional to concentration: Aλ = ClσScript error: No such module "Check for unknown parameters"., where AλScript error: No such module "Check for unknown parameters". is the absorbance at a given wavelength λScript error: No such module "Check for unknown parameters"., CScript error: No such module "Check for unknown parameters". is the concentration as a number density, and lScript error: No such module "Check for unknown parameters". is the path length. The extinction or absorbance of the radiation is the logarithm (decadic or, more usually, natural) of the reciprocal of the transmittance Template:Mathcal:[4]
Relation to physical size
There is no simple relationship between the scattering cross section and the physical size of the particles, as the scattering cross section depends on the wavelength of radiation used. This can be seen when looking at a halo surrounding the Moon on a decently foggy evening: Red light photons experience a larger cross sectional area of water droplets than photons of higher energy. The halo around the Moon thus has a perimeter of red light due to lower energy photons being scattering further from the center of the Moon. Photons from the rest of the visible spectrum are left within the center of the halo and perceived as white light.
Meteorological range
The scattering cross section is related to the meteorological range LVScript error: No such module "Check for unknown parameters".:
The quantity CσscatScript error: No such module "Check for unknown parameters". is sometimes denoted bscatScript error: No such module "Check for unknown parameters"., the scattering coefficient per unit length.[9]
Examples
Elastic collision of two hard spheres
The following equations apply to two hard spheres that undergo a perfectly elastic collision.Template:Sfn Let RScript error: No such module "Check for unknown parameters". and rScript error: No such module "Check for unknown parameters". denote the radii of the scattering center and scattered sphere, respectively. The differential cross section is
and the total cross section is
In other words, the total scattering cross section is equal to the area of the circle (with radius r + RScript error: No such module "Check for unknown parameters".) within which the center of mass of the incoming sphere has to arrive for it to be deflected.
Rutherford scattering
In Rutherford scattering, an incident particle with charge qScript error: No such module "Check for unknown parameters". and energy EScript error: No such module "Check for unknown parameters". scatters off a fixed particle with charge QScript error: No such module "Check for unknown parameters".. The differential cross section is
where is the vacuum permittivity.Template:Sfn The total cross section is infinite unless a cutoff for small scattering angles is applied.Template:Sfn This is due to the long range of the Coulomb potential.
Scattering from a 2D circular mirror
The following example deals with a beam of light scattering off a circle with radius rScript error: No such module "Check for unknown parameters". and a perfectly reflecting boundary. The beam consists of a uniform density of parallel rays, and the beam-circle interaction is modeled within the framework of geometric optics. Because the problem is genuinely two-dimensional, the cross section has unit of length (e.g., metre). Let αScript error: No such module "Check for unknown parameters". be the angle between the light ray and the radius joining the reflection point of the ray with the center point of the mirror. Then the increase of the length element perpendicular to the beam is
The reflection angle of this ray with respect to the incoming ray is 2αScript error: No such module "Check for unknown parameters"., and the scattering angle is
The differential relationship between incident and reflected intensity IScript error: No such module "Check for unknown parameters". is
The differential cross section is therefore (dΩ = dθScript error: No such module "Check for unknown parameters".)
Its maximum at θ = πScript error: No such module "Check for unknown parameters". corresponds to backward scattering, and its minimum at θ = 0Script error: No such module "Check for unknown parameters". corresponds to scattering from the edge of the circle directly forward. This expression confirms the intuitive expectations that the mirror circle acts like a diverging lens. The total cross section is equal to the diameter of the circle:
Scattering from a 3D spherical mirror
The result from the previous example can be used to solve the analogous problem in three dimensions, i.e., scattering from a perfectly reflecting sphere of radius aScript error: No such module "Check for unknown parameters"..
The plane perpendicular to the incoming light beam can be parameterized by cylindrical coordinates rScript error: No such module "Check for unknown parameters". and φScript error: No such module "Check for unknown parameters".. In any plane of the incoming and the reflected ray we can write (from the previous example):
while the impact area element is
In spherical coordinates,
Together with the trigonometric identity
we obtain
The total cross section is
See also
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- Cross section (geometry)
- Flow velocity
- Luminosity (scattering theory)
- Linear attenuation coefficient
- Mass attenuation coefficient
- Neutron cross section
- Nuclear cross section
- Gamma ray cross section
- Partial wave analysis
- Particle detector
- Radar cross-section
- Rutherford scattering
- Scattering amplitude
References
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- ↑ H.J.W. Müller-Kirsten, Introduction to Quantum Mechanics: Schrödinger Equation and Path Integral, 2nd edition (2012) World Scientific; pp. 271 - 272, 311 - 314.
- ↑ Script error: No such module "citation/CS1".
- ↑ Nondestructive Testing Handbook Volume 4 Radiographic Testing, ASNT, 2002, chapter 22.
- ↑ a b Script error: No such module "citation/CS1".
- ↑ Bohren, Craig F., and Donald R. Huffman. Absorption and scattering of light by small particles. John Wiley & Sons, 2008.
- ↑ Script error: No such module "Citation/CS1".
- ↑ Script error: No such module "Citation/CS1".
- ↑ Script error: No such module "Citation/CS1".
- ↑ IUPAC, Compendium of Chemical Terminology, 5th ed. (the "Gold Book") (2025). Online version: (2006–) "Scattering cross section, σscatScript error: No such module "Check for unknown parameters".". Script error: No such module "CS1 identifiers".Script error: No such module "TemplatePar".
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Bibliography
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- Script error: No such module "citation/CS1".
- Script error: No such module "citation/CS1".
- J. D. Bjorken, S. D. Drell, Relativistic Quantum Mechanics, 1964
- P. Roman, Introduction to Quantum Theory, 1969
- W. Greiner, J. Reinhardt, Quantum Electrodynamics, 1994
- R. G. Newton. Scattering Theory of Waves and Particles. McGraw Hill, 1966.
- Script error: No such module "citation/CS1".
External links
- Nuclear Cross Section
- Scattering Cross Section
- IAEA – Nuclear Data Services
- BNL – National Nuclear Data Center
- Particle Data Group – The Review of Particle Physics
- IUPAC Goldbook – Definition: Reaction Cross Section
- IUPAC Goldbook – Definition: Collision Cross Section
- ShimPlotWell cross section plotter for nuclear data