Palladium(II) nitrate

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Palladium(II) nitrate
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Molar mass 230.43 g/mol
Appearance yellow solid
Density 3.546 g/cm3[1]
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Template:Longitem Palladium(II) chloride
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Palladium(II) nitrate is the inorganic compound with the formula Pd(NO3)2.(H2O)x where x = 0 or 2. The anhydrous and dihydrate are deliquescent solids. According to X-ray crystallography, both compounds feature square planar Pd(II) with unidentate nitrate ligands. The anhydrous compound, which is a coordination polymer, is yellow.[1][2]

As a solution in nitric acid, Pd(NO3)2 catalyzes the conversion of alkenes to dinitrate esters. Its pyrolysis affords palladium oxide.[3]

Preparation

Hydrated palladium nitrate may be prepared by dissolving palladium oxide hydrate in dilute nitric acid followed by crystallization. The nitrate crystallizes as yellow-brown deliquescent prisms. The anhydrous material is obtained by treating palladium metal with fuming nitric acid.[1]

References

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  1. ↑ a b c Script error: No such module "Citation/CS1".
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  3. ↑ Timothy T. Wenzel "Palladium(II) Nitrate" Encyclopedia of Reagents for Organic Synthesis 2001, John Wiley & Sons. Script error: No such module "CS1 identifiers".

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