Methyl butyrate

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Methyl butyrate[1]
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MeSH C043811
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Template:Longitem Template:Chembox Elements/molecular formula
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Appearance Colorless liquid
Density 0.898 g/cm3
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Template:Longitem −66.4×10−6 cm3/mol
Template:Longitem 1.386
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Methyl butyrate, also known under the systematic name methyl butanoate, is the methyl ester of butyric acid. Like most esters, it has a fruity odor, in this case resembling apples or pineapples.[2] At room temperature, it is a colorless liquid with low solubility in water, upon which it floats to form an oily layer. Although it is flammable, it has a relatively low vapor pressure (40 mmHg at Script error: No such module "convert".), so it can be safely handled at room temperature without special safety precautions.[3]

Methyl butyrate is present in small amounts in several plant products, especially pineapple oil.[4] It can be produced by distillation from essential oils of vegetable origin, but is also manufactured on a small scale for use in perfumes[5] and as a food flavoring.

Methyl butyrate has been used in combustion studies as a surrogate fuel for the larger fatty acid methyl esters found in biodiesel.[6] However, studies have shown that, due to its short-chain length, methyl butyrate does not reproduce well the negative temperature coefficient (NTC) behaviour and early CO2 formation characteristics of real biodiesel fuels. Therefore, methyl butyrate is not a suitable surrogate fuel for biodiesel combustion studies.[7]

References

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  1. Merck Index, 13th Edition
  2. Methyl butyrate, thegoodscentscompany.com
  3. Aldrich Chemicals Handbook, Sigma-Aldrich Company, Milwaukee, (2007)
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  6. Methyl butyrate as a component of biodiesel Script error: No such module "webarchive".
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