Lithium sulfide
(Redirected from Lithium sulphide)
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Lithium sulfide is the inorganic compound with the formula Li2S. It crystallizes in the antifluorite motif, described as the salt (Li+)2S2−. It forms a solid yellow-white deliquescent powder. In air, it easily hydrolyses to release foul smelling hydrogen sulfide gas.[1]
Preparation
Lithium sulfide is prepared by treating lithium with sulfur. This reaction is conveniently conducted in anhydrous ammonia.[2]
- 2 Li + S → Li2S
The THF-soluble triethylborane adduct of lithium sulfide can be generated using superhydride.[3]
Reactions and applications
Lithium sulfide has been considered for use in lithium–sulfur batteries.[4]
References
- ↑ Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. Template:ISBN.
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