1-Bromohexane

1-Bromohexane
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Template:Longitem	1731290
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MeSH	1-bromohexane
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UN number	1993
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Template:Longitem	Template:Chembox Elements/molecular formula
Molar mass	Template:Chem molar mass
Appearance	Colorless liquid
Density	1.176 g/mL
Melting point	Template:Chembox CalcTemperatures
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Solubility	Alcohol, ether
Template:Longitem	1.448 (20 °C, D)
Template:Longitem	219.7 J K−1 mol−1
Template:Longitem	452.92 J K−1 mol−1
Template:Longitem	−196.1–−192.9 kJ mol−1
Template:Longitem	−4026.2–−4023.0 kJ mol−1
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Flash point	Template:Chembox CalcTemperatures
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1-Bromohexane is organobromine compound with formula Br(CH₂)₅CH₃. It is a colorless liquid.

Synthesis and reactions

Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.^[2]

1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents.^[3] It reacts with potassium fluoride to give the corresponding fluorocarbons.^[4]

References

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↑ Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113, 5392-5397.
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[3] Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113, 5392-5397.

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[2]

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1-Bromohexane

Synthesis and reactions

See also

References

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1-Bromohexane

Synthesis and reactions

See also

References

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