1-Bromohexane
(Redirected from Hexyl bromide)
Template:Short description <templatestyles src="Chembox/styles.css"/>
Template:Chembox image cellTemplate:Chembox image cellTemplate:Chembox AllOtherNamesTemplate:Chembox headerbarTemplate:Chembox IndexlistTemplate:Chembox JmolTemplate:Chembox ChEMBLTemplate:Chembox ECHATemplate:Chembox E numberTemplate:Chembox IUPHAR ligandTemplate:Chembox UNIITemplate:Chembox CompToxTemplate:Chembox headerbarTemplate:Chembox SolubilityInWaterTemplate:Chembox headerbarTemplate:Chembox HazardsTemplate:Chembox headerbarTemplate:Chembox Datapage checkTemplate:Yesno| Template:Longitem | Template:Unbulleted list |
| Template:Longitem | 1731290 |
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| MeSH | 1-bromohexane |
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| UN number | 1993 |
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| Template:Longitem | Template:Chembox Elements/molecular formula |
| Molar mass | Template:Chem molar mass |
| Appearance | Colorless liquid |
| Density | 1.176 g/mL |
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| Solubility | Alcohol, ether |
| Template:Longitem | 1.448 (20 °C, D) |
| Template:Longitem | 219.7 J K−1 mol−1 |
| Template:Longitem | 452.92 J K−1 mol−1 |
| Template:Longitem | −196.1–−192.9 kJ mol−1 |
| Template:Longitem | −4026.2–−4023.0 kJ mol−1 |
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1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.[2]
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents.[3] It reacts with potassium fluoride to give the corresponding fluorocarbons.[4]
See also
References
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- ↑ Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113, 5392-5397.
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