1-Butyne
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| UN number | 2452 |
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| Template:Longitem | C4H6 |
| Molar mass | 54.091 g/mol |
| Odor | Acetylenic[1] |
| Density | 0.6783 g cm−3[2] |
| Melting point | Template:Chembox CalcTemperatures |
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1-Butyne is an organic compound with the formula Template:Chem2. It is a terminal alkyne. The compound is a common terminal alkyne substrate in diverse studies of catalysis. It is a colorless combustible gas.[2] In 2017, Script error: No such module "convert". was produced in the USA.[4]
1-Butyne participates in reactions typical for terminal alkynes, such as alkyne metathesis,[5] hydrogenation, condensation with formaldehyde. Based on its heat of combustion, it is slightly more stable than its isomer 2-butyne.[6]
The combustion of 1-Butyne produces propargyl radicals, a pre-cursor to soot and polycyclic aromatic hydrocarbons, as the propargyl radicals can form basic aromatic rings, making butyne's fuel usage a concern for emissions.[7]
1-Butyne is in unsaturated C4 petroleum cuts, and has to be separated out in industrial hydrorefining to make 1-butene, which is used to make low density polyethylene and polybutene. Distillation is impractical due to similar boiling points, so 1-butyne is removed by catalytic hydrogenation.[8] Usually the catalyst is palladium, operated with liquid hydrocarbon and hydrogen gas at 20-60°C and pressures up to 10 bar.[9]
See also
References
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- ↑ Gangolli, S.. (2005). Dictionary of Substances and Their Effects (DOSE, 3rd Electronic Edition). Royal Society of Chemistry (RSC). Retrieved from here
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External links
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