Aluminium oxynitride

Aluminium oxynitride (marketed under the name ALON by Surmet Corporation) is a transparent ceramic composed of aluminium, oxygen and nitrogen. Aluminium oxynitride is optically transparent (≥80% for 2 mm thickness) in the near-ultraviolet, visible, and mid-wave-infrared regions of the electromagnetic spectrum. It is four times as hard as fused silica glass, 85% as hard as sapphire, and nearly 115% as hard as magnesium aluminate spinel. It can be fabricated into transparent windows, plates, domes, rods, tubes, and other forms using conventional ceramic powder processing techniques.

Aluminium oxynitride is the hardest polycrystalline transparent ceramic available commercially.Template:Updateinline Because of its relatively low weight, distinctive optical and mechanical properties, and resistance to oxidation or radiation, it shows promise for applications such as bulletproof, blast-resistant, and optoelectronic windows. Aluminium oxynitride-based armor has been shown to stop multiple armor-piercing projectiles of up to .50 BMG.

Properties

Aluminium oxynitride is resistant to various acids, bases, and water.

Mechanical

Aluminium oxynitride has the following mechanical properties:

• Compressive strength 2.68 GPa
• Flexural strength 0.38–0.7 GPa
• Fracture toughness 2.0 MPa·m^1/2
• Knoop hardness 1800 kg/mm² (0.2 kg load)
• Poisson ratio 0.24
• Shear modulus 135 GPa
• Young's modulus 334 GPa

Thermal and optical

Aluminium oxynitride has the following thermal and optical properties:

• Specific heat 0.781 J/(g·K)
• Thermal conductivity 12.3 W/(m·K)
• Thermal expansion coefficient ~4.7Template:E/K
• Transparency range 200–5000 nm

Applications

Aluminium oxynitride is used for infrared-optical windows, with greater than 80% transparency for 2 mm thickness at wavelengths below about 4 micrometers, dropping to near zero at about 6 micrometers. It has also been demonstrated as an interface passivation layer in some semiconductor-related applications.

Aluminium oxynitride has less than half the weight and thickness of glass-based transparent armor. Aluminium oxynitride armor of Template:Convert thickness is capable of stopping .50 BMG armor-piercing rounds, which can penetrate Template:Convert of traditional glass laminate.

In 2005, the United States Air Force began testing aluminium-oxynitride-based armor.

Manufacture

Aluminium oxynitride can be fabricated as windows, plates, domes, rods, tubes and other forms using conventional ceramic powder processing techniques. Its composition can vary slightly: the aluminium content from about 30% to 36%, which has been reported to affect the bulk and shear moduli by only 1–2%. The fabricated greenware is subjected to heat treatment (densification) at elevated temperatures followed by grinding and polishing to transparency. It can withstand temperatures of about Template:Convert in inert atmospheres. The grinding and polishing substantially improves the impact resistance and other mechanical properties of armor.

Patents

Patents related to aluminium oxynitride include:

• Aluminium oxynitride having improved optical characteristics and method of manufacture TM Hartnett, RL Gentilman U.S. patent 4481300, 1984
• Process for producing polycrystalline cubic aluminium oxynitride JW McCauley U.S. patent 4241000, 1980
• Transparent aluminium oxynitride and method of manufacture RL Gentilman, EA Maguire U.S. patent 4520116, 1985; U.S. patent 4720362, 1988
• Transparent aluminium oxynitride-based ceramic article JP Mathers U.S. patent 5231062, 1993

See also

• Aluminium nitride
• Corundum
• Transparent ceramics
• Transparent aluminum (material in Star Trek)
• Gorilla Glass

External links

• Processing of Optically Transparent Aluminum Oxynitride
• "Solubility Limits of La and Y in Aluminum Oxynitride (AlON) at 1870°C". Lior Miller and Wayne D. Kaplan. Department of Materials Engineering, Technion, Haifa, Israel, 2006.
• The Influence of Sintering Additives on the Microstructure and Properties of ALON. Yechezkel Ashuach. Master's Thesis, Technion – Israel Institute of Technology, 2003.