1-Bromohexane

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1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.

Synthesis and reactions

Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.[1]

1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents.[2] It reacts with potassium fluoride to give the corresponding fluorocarbons.[3]

See also

References

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  2. Garst, J., Ungvary, F., Batlaw, R., & Lawrence, K. (1991). Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. Journal of American Chemical Society, 113, 5392-5397.
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