imported>MrSwedishMeatballs at 19:37, 7 March 2025

2025-03-07T19:37:38Z

New page

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 432484439
| ImageFileL1 = Selenium-hexafluoride-2D.png
| ImageSizeL1 =
| ImageFileR1 = Selenium-hexafluoride-3D-balls.png
| ImageSizeR1 =
| IUPACName = Selenium hexafluoride
| OtherNames = Selenium(VI) fluoride, Selenium fluoride
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 7783-79-1
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = H91D37I668
| PubChem = 24558
| RTECS = VS9450000
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 22964
| InChIKey = LMDVZDMBPZVAIV-UHFFFAOYAP
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/F6Se/c1-7(2,3,4,5)6
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = LMDVZDMBPZVAIV-UHFFFAOYSA-N
| SMILES = F[Se](F)(F)(F)(F)F
| InChI = 1S/F6Se/c1-7(2,3,4,5)6
}}
|Section2={{Chembox Properties
| Formula = SeF6
| MolarMass = 192.9534 g/mol
| Appearance = colourless gas
| Density = 7.887 g/L<ref name=CRC>{{RubberBible86th}}</ref>
| MeltingPtC = -39
| BoilingPtC = -34.5
| BoilingPt_notes = sublimes
| Solubility = insoluble
| RefractIndex = 1.895
| VaporPressure = >1 atm (20°C)<ref name=PGCH/>
| MagSus = −51.0·10−6 cm3/mol
}}
|Section3={{Chembox Structure
| CrystalStruct = [[Orthorhombic]], [[Pearson symbol|oP28]]
| SpaceGroup = Pnma, No. 62
| Coordination = octahedral (''Oh'')
| Dipole = 0
}}
|Section7={{Chembox Hazards
| MainHazards = toxic, corrosive
| FlashPt =
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0
| AutoignitionPt =
| IDLH = 2 ppm<ref name=PGCH>{{PGCH|0551}}</ref>
| REL = TWA 0.05 ppm<ref name=PGCH/>
| PEL = TWA 0.05 ppm (0.4 mg/m3)<ref name=PGCH/>
| LCLo = 10 ppm (rat, 1 hr) 10 ppm (mouse, 1 hr) 10 ppm (guinea pig, 1 hr)<ref>{{IDLH|7783791|Selenium hexafluoride}}</ref>
}}
|Section4={{Chembox Thermochemistry
| DeltaHf = −1030 kJ/mol<ref name = "Wiberg&Holleman">{{ cite book |author1=Wiberg, E. |author2=Holleman, A. F. | title = Inorganic Chemistry | year = 2001 | publisher = Elsevier | isbn = 0-12-352651-5 }}</ref>
| DeltaHc =
| Entropy =
| HeatCapacity =
}}
}}

'''Selenium hexafluoride''' is the [[inorganic compound]] with the [[chemical formula|formula]] SeF6. It is a very toxic colourless gas described as having a "repulsive" odor.<ref name="decompose">{{ cite web | url = http://www.cpcb.nic.in/divisionsofheadoffice/pci-ssi/MATERIAL_SAFETY-DATABASE/MSDS2008/558.pdf | title = Material Safety | access-date = 2010-07-24 }}</ref> It is not widely encountered and has no commercial applications.<ref>{{ Ullmann | author = Langner, B. E. | title = Selenium and Selenium Compounds | doi = 10.1002/14356007.a23_525 }}</ref>

==Structure, preparation, and reactions==
SeF6 has [[octahedral molecular geometry]] with an Se−F bond length of 168.8 [[picometer|pm]]. In terms of bonding, it is [[hypervalent molecule|hypervalent]].

SeF6 can be prepared from the elements.<ref>{{ Cite book |author1=Yost, D. M. |author2=Simons, J. H. |title=Inorganic Syntheses | chapter = Sulfur, Selenium, and Tellurium Hexafluorides | year = 1939 | volume = 1 | pages = 121–122 | doi = 10.1002/9780470132326.ch44 |isbn=9780470132326 }}</ref> It also forms by the reaction of [[bromine trifluoride]] (BrF3) with [[selenium dioxide]]. The crude product can be purified by sublimation.

The relative reactivity of the hexafluorides of S, Se, and Te follows the order [[tellurium hexafluoride|TeF6]] > SeF6 > [[sulfur hexafluoride|SF6]], the latter being completely inert toward hydrolysis until high temperatures. SeF6 also resists hydrolysis.<ref name = "Wiberg&Holleman"/> The gas can be passed through 10% NaOH or KOH without change, but reacts with gaseous [[ammonia]] at 200 °C.<ref name = "Krebs">{{ cite encyclopedia |author1=Krebs, B. |author2=Bonmann, S. |author3=Eidenschink, I. | title = Selenium-Inorganic Chemistry | encyclopedia = Encyclopedia of Inorganic Chemistry | editor = King, R. B. | year = 1994 | publisher = John Wiley & Sons | isbn = 0-471-93620-0 }}</ref>

==Safety==
Although selenium hexafluoride is quite inert and slow to hydrolyze, it is toxic even at low concentrations,<ref name="toxic">{{cite web | url = http://www.atsdr.cdc.gov/MMG/MMG.asp?id=1015&tid=215 | archive-url = https://web.archive.org/web/20100528071037/http://www.atsdr.cdc.gov/MMG/MMG.asp?id=1015&tid=215 | url-status = dead | archive-date = May 28, 2010 | title = Medical Management Guidelines for Selenium Hexafluoride (SeF6) | publisher = CDC ATSDR | access-date = 2010-07-24 }}</ref> especially by longer exposure. In the U.S., [[Occupational Safety and Health Administration|OSHA]] and [[ACGIH]] standards for selenium hexafluoride exposure is an upper limit of 0.05 ppm in air averaged over an eight-hour work shift. Additionally, selenium hexafluoride is designated as [[Immediately Dangerous to Life and Health|IDLH]] chemical with a maximum allowed exposure limit of 2 ppm.<ref>[https://www.cdc.gov/niosh/idlh/7783791.html Documentation for Immediately Dangerous To Life or Health Concentrations (IDLHs)]</ref>

==References==
{{reflist}}

==External links==
* [https://www.atsdr.cdc.gov/toxfaqs/tfacts183.pdf ATSDR ToxFAQs - Selenium Hexafluoride] U.S. [[Department of Health and Human Services]]
* [https://www.cdc.gov/niosh/npg/npgd0551.html CDC - NIOSH Pocket Guide to Chemical Hazards] U.S. [[Department of Health and Human Services]]
* [http://webbook.nist.gov/cgi/cbook.cgi?ID=C7783791 WebBook page for SeF6]

{{Hexafluorides}}
{{Selenium compounds}}
{{fluorine compounds}}

[[Category:Selenium(VI) compounds]]
[[Category:Hexafluorides]]
[[Category:Octahedral compounds]]
[[Category:Chalcohalides]]
[[Category:Selenium halides]]
[[Category:Foul-smelling chemicals]]

Selenium hexafluoride - Revision history

imported>MrSwedishMeatballs at 19:37, 7 March 2025