View source for National Emissions Standards for Hazardous Air Pollutants

{{Short description|US EPA air pollutant emission standards}}
{{Refimprove|date=April 2022}}
The '''National Emission Standards for Hazardous Air Pollutants''' ('''NESHAP''') are [[air pollution]] standards issued by the [[United States Environmental Protection Agency]] (EPA). The standards, authorized by the [[Clean Air Act (1970)|Clean Air Act]], are for pollutants not covered by the [[National Ambient Air Quality Standards]] (NAAQS) that may cause an increase in fatalities or in serious, irreversible, or incapacitating illness.<ref name="CAA 112">United States. Clean Air Amendments of 1970. {{USPL|91|604}} Section 112. {{USC|42|7412}}</ref>

==Maximum Achievable Control Technology standards==
The standards for a particular source category require the maximum degree of emission reduction that the EPA determines to be achievable, which is known as the Maximum Achievable Control Technology (MACT) standards.<ref name="EPA-reducing emissions">{{cite web |title= Reducing Emissions of Hazardous Air Pollutants |url= https://www.epa.gov/haps/reducing-emissions-hazardous-air-pollutants |date=2021-01-26 |publisher=United States Environmental Protection Agency (EPA) |location=Washington, D.C.}}</ref> These standards are authorized by Section 112 of the 1970 Clean Air Act and the regulations are published in the [[Code of Federal Regulations]] (CFR).<ref>EPA. "National Emission Standards for Hazardous Air Pollutants." ''Code of Federal Regulations,'' {{USCFR|40|61}}. “National Emission Standards for Hazardous Air Pollutants for Source Categories.” {{USCFR|40|63}}</ref>

===Pollutants===
EPA regulates the following hazardous air pollutants with the MACT standards.

{| class="wikitable"
|-
![[CAS Number]] !!Chemical Name !!Notes
|-
|75-07-0   ||[[Acetaldehyde]]
|-
|60-35-5   ||[[Acetamide]]
|-
|75-05-8   ||[[Acetonitrile]]
|-
|98-86-2   ||[[Acetophenone]] (Methyl Phenyl Ketone)
|-
|53-96-3   ||[[2-Acetylaminofluorene]]
|-
|107-02-8  ||[[Acrolein]]
|-
|79-06-1   ||[[Acrylamide]]
|-
|79-10-7   ||[[Acrylic acid]]
|-
|107-13-1  ||[[Acrylonitrile]]
|-
|107-05-1  ||[[Allyl chloride]] (3-Chloropropene)
|-
|92-67-1   ||[[4-Aminobiphenyl]]
|-
|62-53-3   ||[[Aniline]]
|-
|90-04-0   ||[[o-Anisidine]]
|-
|1332-21-4 ||[[Asbestos]]
|-
|71-43-2   ||[[Benzene]] ||including benzene from gasoline
|-
|92-87-5   ||[[Benzidine]]
|-
|98-07-7   ||[[Benzotrichloride]]
|-
|100-44-7  ||[[Benzyl chloride]]
|-
|92-52-4   ||[[Biphenyl]]
|-
|117-81-7  ||[[Bis(2-ethylhexyl)phthalate]] (DEHP)
|-
|542-88-1  ||[[Bis(chloromethyl)ether]]
|-
|75-25-2   ||[[Bromoform]] (Tribromomethane)
|-
|106-99-0  ||[[1,3-Butadiene]]
|-
|156-62-7  ||[[Calcium cyanamide]]
|-
|105-60-2  ||[[Caprolactam]] ||Delisted on June 18, 1996
|-
|133-06-2  ||[[Captan]]
|-
|63-25-2   ||[[Carbaryl]]
|-
|75-15-0   ||[[Carbon disulfide]]
|-
|56-23-5   ||[[Carbon tetrachloride]] (Tetrachloromethane)
|-
|463-58-1  ||[[Carbonyl sulfide]]
|-
|120-80-9  ||[[Pyrocatechol|Catechol]]
|-
|133-90-4  ||[[Chloramben]]
|-
|57-74-9   ||[[Chlordane]]
|-
|7782-50-5 ||[[Chlorine]]
|-
|79-11-8   ||[[Chloroacetic acid]]
|-
|532-27-4  ||[[CN gas|2-Chloroacetophenone]]
|-
|108-90-7  ||[[Chlorobenzene]]
|-
|510-15-6  ||[[Chlorobenzilate]]
|-
|67-66-3   ||[[Chloroform]] (Trichloromethane)
|-
|107-30-2  ||[[Chloromethyl methyl ether]]
|-
|126-99-8  ||[[Chloroprene]]
|-
|1319-77-3 ||[[Cresol]]s/Cresylic acid (isomers and mixture)
|-
|95-48-7   ||[[Cresol|o-Cresol]]
|-
|108-39-4  ||[[Cresol|m-Cresol]]
|-
|106-44-5  ||[[Cresol|p-Cresol]]
|-
|98-82-8   ||[[Cumene]]
|-
|94-75-7   ||[[2,4-Dichlorophenoxyacetic acid|2,4-D]], salts and esters
|-
|3547-04-4 ||[[Dichlorodiphenyldichloroethylene]] (DDE)
|-
|334-88-3  ||[[Diazomethane]]
|-
|132-64-9  ||[[Dibenzofuran]]s
|-
|96-12-8   ||[[1,2-Dibromo-3-chloropropane]] (DBCP)
|-
|84-74-2   ||[[Dibutyl phthalate|Dibutylphthalate]]
|-
|106-46-7  ||[[1,4-Dichlorobenzene]] (p-Dichlorobenzene)
|-
|91-94-1   ||[[3,3'-Dichlorobenzidine]]
|-
|111-44-4  ||[[Dichloroethyl ether]] (Bis(2-chloroethyl)ether)
|-
|542-75-6  ||[[1,3-Dichloropropene]]
|-
|62-73-7   ||[[Dichlorvos]]
|-
|111-42-2  ||[[Diethanolamine]]
|-
|64-67-5   ||[[Diethyl sulfate]]
|-
|119-90-4  ||[[3,3'-Dimethoxybenzidine]]
|-
|60-11-7   ||[[Methyl yellow|Dimethyl aminoazobenzene]]
|-
|119-93-7  ||[[3,3'-Dimethyl ben]]zidine
|-
|79-44-7   ||Dimethyl[[carbamoyl chloride]]
|-
|68-12-2   ||[[Dimethylformamide|Dimethyl formamide]]
|-
|57-14-7   ||[[Unsymmetrical dimethylhydrazine|1,1-Dimethyl hydrazine]]
|-
|131-11-3  ||[[Dimethyl phthalate]]
|-
|77-78-1   ||[[Dimethyl sulfate]]
|-
|121-69-7  ||[[Dimethylaniline|N,N-Dimethylaniline]] ||Clean Air Act erroneously lists N,N-Diethylaniline
|-
|534-52-1  ||[[4,6-Dinitro-o-cresol]], and salts
|-
|51-28-5   ||[[2,4-Dinitrophenol]]
|-
|121-14-2  ||[[Dinitrotoluene|2,4-Dinitrotoluene]]
|-
|123-91-1  ||[[1,4-Dioxane]] (1,4-Diethyleneoxide)
|-
|122-66-7  ||[[1,2-Diphenylhydrazine]]
|-
|106-89-8  ||[[Epichlorohydrin]] (l-Chloro-2,3-epoxypropane)
|-
|106-88-7  ||[[1,2-Epoxybutane]]
|-
|140-88-5  ||[[Ethyl acrylate]]
|-
|100-41-4  ||[[Ethylbenzene|Ethyl benzene]]
|-
|51-79-6   ||[[Ethyl carbamate]] (Urethane)
|-
|75-00-3   ||[[Chloroethane|Ethyl chloride]] (Chloroethane)
|-
|106-93-4  ||[[1,2-Dibromoethane|Ethylene dibromide]] (1,2-Dibromoethane)
|-
|107-06-2  ||[[1,2-Dichloroethane|Ethylene dichloride]] (1,2-Dichloroethane)
|-
|107-21-1  ||[[Ethylene glycol]]
|-
|151-56-4  ||[[Aziridine|Ethylene imine]] (Aziridine)
|-
|75-21-8   ||[[Ethylene oxide]]
|-
|96-45-7   ||[[Ethylene thiourea]]
|-
|75-34-3   ||[[1,1-Dichloroethane|Ethylidene dichloride]] (1,1-Dichloroethane)
|-
|50-00-0   ||[[Formaldehyde]]
|-
|76-44-8   ||[[Heptachlor]]
|-
|118-74-1  ||[[Hexachlorobenzene]]
|-
|87-68-3   ||[[Hexachlorobutadiene]]
|-
|77-47-4   ||[[Hexachlorocyclopentadiene]]
|-
|67-72-1   ||[[Hexachloroethane]]
|-
|822-06-0  ||[[Hexamethylene diisocyanate|Hexamethylene-1,6-diisocyanate]]
|-
|680-31-9  ||[[Hexamethylphosphoramide]]
|-
|110-54-3  ||[[Hexane]]
|-
|302-01-2  ||[[Hydrazine]]
|-
|7647-01-0 ||[[Hydrogen chloride|Hydrochloric acid]]
|-
|7664-39-3 ||[[Hydrogen fluoride]] (Hydrofluoric acid)
|-
|7783-06-4 ||[[Hydrogen sulfide]] ||Delisted on December 4, 1991
|-
|123-31-9  ||[[Hydroquinone]]
|-
|78-59-1   ||[[Isophorone]]
|-
|58-89-9   ||[[Lindane]] (all isomers)
|-
|108-31-6  ||[[Maleic anhydride]]
|-
|67-56-1   ||[[Methanol]]
|-
|72-43-5   ||[[Methoxychlor]]
|-
|74-83-9   ||[[Bromomethane|Methyl bromide]] (Bromomethane)
|-
|74-87-3   ||[[Chloromethane|Methyl chloride]] (Chloromethane)
|-
|71-55-6   ||[[1,1,1-Trichloroethane|Methyl chloroform]] (1,1,1-Trichloroethane)
|-
|78-93-3   ||[[Butanone|Methyl ethyl ketone]] (2-Butanone or MEK) ||Delisted on December 19, 2005
|-
|60-34-4   ||[[Monomethylhydrazine|Methyl hydrazine]]
|-
|74-88-4   ||[[Iodomethane|Methyl iodide]] (Iodomethane)
|-
|108-10-1  ||[[Methyl isobutyl ketone]] (Hexone or MIBK) ||currently under review for delisting
|-
|624-83-9  ||[[Methyl isocyanate]]
|-
|80-62-6   ||[[Methyl methacrylate]]
|-
|1634-04-4 ||[[Methyl tert-butyl ether]]
|-
|101-14-4  ||[[4,4'-Methylene bis(2-chloroaniline)]]
|-
|75-09-2   ||[[Dichloromethane|Methylene chloride]] (Dichloromethane)
|-
|101-68-8  ||[[Methylene diphenyl diisocyanate]] (MDI) ||currently under review for delisting
|-
|101-77-9  ||[[4,4'-Methylenedianiline]]
|-
|91-20-3   ||[[Naphthalene]]
|-
|98-95-3   ||[[Nitrobenzene]]
|-
|92-93-3   ||[[4-Nitrobiphenyl]]
|-
|100-02-7  ||[[4-Nitrophenol]]
|-
|79-46-9   ||[[2-Nitropropane]]
|-
|684-93-5  ||[[N-Nitroso-N-methylurea]]
|-
|62-75-9   ||[[N-Nitrosodimethylamine]]
|-
|59-89-2   ||[[N-Nitrosomorpholine]]
|-
|56-38-2   ||[[Parathion]]
|-
|82-68-8   ||[[Pentachloronitrobenzene]] (Quintobenzene)
|-
|87-86-5   ||[[Pentachlorophenol]]
|-
|108-95-2  ||[[Phenol]]
|-
|106-50-3  ||[[p-Phenylenediamine]]
|-
|75-44-5   ||[[Phosgene]]
|-
|7803-51-2 ||[[Phosphine]]
|-
|7723-14-0 ||[[Phosphorus]]
|-
|85-44-9   ||[[Phthalic anhydride]]
|-
|1336-36-3 ||[[Polychlorinated biphenyls]] (Aroclors)
|-
|1120-71-4 ||[[1,3-Propane sultone]]
|-
|57-57-8   ||[[beta-Propiolactone]]
|-
|123-38-6  ||[[Propionaldehyde]]
|-
|114-26-1  ||[[Propoxur]] (Baygon)
|-
|78-87-5   ||[[1,2-Dichloropropane|Propylene dichloride]] (1,2-Dichloropropane)
|-
|75-56-9   ||[[Propylene oxide]]
|-
|75-55-8   ||[[1,2-Propylenimine]] (2-Methyl aziridine)
|-
|91-22-5   ||[[Quinoline]]
|-
|106-51-4  ||[[1,4-Benzoquinone|Quinone]]
|-
|100-42-5  ||[[Styrene]]
|-
|96-09-3   ||[[Styrene oxide]]
|-
|1746-01-6 ||[[Polychlorinated dibenzodioxins|2,3,7,8-Tetrachlorodibenzo-p-dioxin]]
|-
|79-34-5   ||[[1,1,2,2-Tetrachloroethane]]
|-
|127-18-4  ||[[Tetrachloroethylene]] (Perchloroethylene)
|-
|7550-45-0 ||[[Titanium tetrachloride]]
|-
|108-88-3  ||[[Toluene]]
|-
|95-80-7   ||[[2,4-Toluene diamine]]
|-
|584-84-9  ||[[Toluene diisocyanate|2,4-Toluene diisocyanate]]
|-
|95-53-4   ||[[Toluidine|o-Toluidine]]
|-
|8001-35-2 ||[[Toxaphene]] (chlorinated camphene)
|-
|120-82-1  ||[[1,2,4-Trichlorobenzene]]
|-
|79-00-5   ||[[1,1,2-Trichloroethane]]
|-
|79-01-6   ||[[Trichloroethylene]]
|-
|95-95-4   ||2,4,5-Trichlorophenol
|-
|88-06-2   ||2,4,6-Trichlorophenol
|-
|121-44-8  ||[[Triethylamine]]
|-
|1582-09-8 ||[[Trifluralin]]
|-
|540-84-1  ||[[2,2,4-Trimethylpentane]]
|-
|108-05-4  ||[[Vinyl acetate]]
|-
|593-60-2  ||[[Vinyl bromide]] (Bromoethene)
|-
|75-01-4   ||[[Vinyl chloride]] (Chloroethene)
|-
|75-35-4   ||[[1,1-Dichloroethylene|Vinylidene chloride]] (1,1-Dichloroethylene)
|-
|1330-20-7 ||[[Xylene]]s (isomers and mixture)
|-
|95-47-6   ||[[Xylene|o-Xylenes]]
|-
|108-38-3  ||[[Xylene|m-Xylenes]]
|-
|106-42-3  ||[[Xylene|p-Xylenes]]
|-
|n/a     ||[[Antimony]] Compounds
|-
|n/a     ||[[Arsenic]] Compounds ||inorganic including [[arsine]]
|-
|n/a     ||[[Beryllium]] Compounds
|-
|n/a     ||[[Cadmium]] Compounds
|-
|n/a     ||[[Chromium]] Compounds
|-
|n/a     ||[[Cobalt]] Compounds
|-
|n/a     ||Coke Oven Emissions
|-
|n/a     ||[[Cyanides|Cyanide]] Compounds{{ref|1|1}}
|-
|n/a     ||[[Glycol ethers]]{{ref|2|2}}
|-
|n/a     ||[[Lead]] Compounds
|-
|n/a     ||[[Manganese]] Compounds
|-
|n/a     ||[[Mercury (element)|Mercury]] Compounds
|-
|n/a     ||Fine mineral fibers{{ref|3|3}}
|-
|n/a     ||[[Nickel]] Compounds
|-
|n/a     ||[[:Category:Polycyclic aromatic compounds|Polycyclic Organic Matter]]{{ref|4|4}}
|-
|n/a     ||[[Radionuclides]]{{ref|5|5}} ||including [[radon]]
|-
|n/a     ||[[Selenium]] Compounds
|}

For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) as part of that chemical's infrastructure.

*{{note|1|1}} X'CN where X = H' or any other group where a formal dissociation may occur. For example, KCN or Ca(CN)<sub>2</sub>
*{{note|2|2}} Includes mono- and di- ethers of [[ethylene glycol]], [[diethylene glycol]], and [[triethylene glycol]] {{chem2|R\s(OCH2CH2)_{n}\sOR'}} where
:n = 1, 2, or 3
:R = alkyl C7 (chain of 7 carbon atoms) or less; or phenyl or alkyl substituted phenyl
:R' = H or alkyl C7 or less; or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Polymers are excluded from the glycol category, as well as surfactant alcohol ethoxylates (where R is an alkyl C8 or greater) and their derivatives, and [[ethylene glycol monobutyl ether]] (CAS 111-76-2).
*{{note|3|3}} Includes mineral fiber emissions from facilities manufacturing or processing glass, rock, or slag fibers (or other mineral derived fibers) of average diameter 1 micrometer or less.
*{{note|4|4}} Includes organic compounds with more than one benzene ring, and which have a boiling point greater than or equal to 100&nbsp;°C. 
*{{note|5|5}} A type of atom which spontaneously undergoes radioactive decay.<ref name="EPA initial list">{{cite web|title=Initial List of Hazardous Air Pollutants with Modifications |url=https://www.epa.gov/haps/initial-list-hazardous-air-pollutants-modifications |date=2022-01-05 |publisher=EPA}}</ref>

==Pollution sources==
Most air toxics originate from human-made sources, including [[Mobile source air pollution|mobile sources]] (e.g., cars, trucks, buses) and stationary sources (e.g., factories, [[Oil refinery|oil refineries]], [[Power station|power plants]]), as well as indoor sources (e.g., building materials and activities such as cleaning). There are two types of stationary sources that generate routine emissions of air toxics:
#'''[[Major stationary source|Major sources]]''' are defined as sources that emit 10 or more tons per year of any of the listed toxic air pollutants, or 25 or more tons per year of a mixture of air toxics. These sources may release air toxics from [[fugitive emission]]s (equipment leaks), when materials are transferred from one location to another, or during discharge through emission stacks or vents.
#'''[[Area source (pollution)|Area sources]]''' consist of smaller facilities that release lesser quantities of toxic pollutants into the air. Area sources are defined as sources that do not emit more than 10 tons per year of a single air toxic or more than 25 tons per year of a combination of air toxics. Although the emissions from individual area sources are often relatively small, collectively their emissions can be of concern, particularly where large numbers of sources are located in heavily populated areas.

EPA published its initial list of source categories in 1992.<ref>EPA (1992-07-16). "Initial List of Categories of Sources Under Section 112(c)(1) of the Clean Air Act Amendments of 1990." ''Federal Register,'' {{USFR|57|31576}}.</ref> Subsequently the agency issued several revisions and updates to the list and the regulatory promulgation schedule. For each listed source category, EPA indicates whether the sources are considered to be major sources or area sources. The [[Clean Air Act (1990)|1990 Clean Air Act Amendments]] direct EPA to set standards for all major sources of air toxics, and for some area sources that are of particular concern. EPA is required to review all source category regulations every eight years.<ref name="EPA review">{{cite web |title=Risk and Technology Review of the National Emissions Standards for Hazardous Air Pollutants |url=https://www.epa.gov/stationary-sources-air-pollution/risk-and-technology-review-national-emissions-standards-hazardous |date=2022-02-08 |website=Stationary Sources of Air Pollution |publisher=EPA}}</ref>

==See also==
*[[Air pollution in the United States]]
*[[Mercury and Air Toxics Standards]]

==References==
{{Reflist}}

==External links==
* [https://www.epa.gov/haps Hazardous Air Pollutants] - EPA

{{Presidency of Richard Nixon}}
{{United States environmental law}}

[[Category:Air pollution in the United States]]
[[Category:Chemical safety]]
[[Category:Emission standards]]
[[Category:Standards of the United States]]
[[Category:United States Environmental Protection Agency]]