Liroconite

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Template:Short description Template:Infobox mineral Liroconite is a complex mineral: Hydrated copper aluminium arsenate hydroxide, with the formula Cu2Al[(OH)4|AsO4]·4(H2O). It is a vitreous monoclinic mineral, colored bright blue to green, often associated with malachite, azurite, olivenite, and clinoclase. It is quite soft, with a Mohs hardness of 2–2.5, and has a specific gravity of 2.9–3.0.

File:Liroconite-Clinoclase-120699.jpg
Vugs in gossan lined with lustrous, blue-green liroconite blades and sparkly, dark blue clinoclase microcrystals from Wheal Gorland (size: 3.4 × 3.0 × 2.0 cm)

It was first identified in 1825 in the tin and copper mines of Devon and Cornwall, England. Although it remains quite rare it has subsequently been identified in a variety of locations including France, Germany, Australia, New Jersey and California.[1]

The type locality for liroconite is Wheal Gorland in St Day, Cornwall in the United Kingdom.[1] The largest crystal specimen on public display is in the Royal Cornwall Museum in Truro.[2]

It occurs as a secondary mineral in copper deposits in association with olivenite, chalcophyllite, clinoclase, cornwallite, strashimirite, malachite, cuprite and limonite.[3]

Structure

Liroconite crystallizes in the monoclinic crystal system.[3]Template:Rp[4] The crystal structure consists of a framework of AsO4 tetrahedra, Jahn-Teller-distorted [CuO2(OH)2(H2O)2] octahedra and [AlO2(OH)4] octahedra.[5]

Unit cell of liroconite

See also

References

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